547) T. Michiyuki, I. Maksso, L. Ackermann, "Photo-Induced Ruthenium-Catalyzed C–H Arylation Polymerization at Ambient Temperature", Angew. Chem. Int. Ed. 2024, in press. Abstract>
546) S. Trienes, J. Xu, L. Ackermann, "Photoinduced C–H arylation of 1,3-azoles via copper/photoredox dual catalysis", Chem. Sci. 2024, in press. Abstract>
545) H. Simon,' A. Zangarelli,' T. Bauch, L. Ackermann, "Ruthenium(II)-Catalyzed Late-Stage Incorporation of N-Aryl Triazoles and Tetrazoles with Sulfonium Salts via C–H Activation", Angew. Chem. Int. Ed. 2024, in press.' These authors contributed equally. Abstract>
544) J. Zakis, A. Messinis, L. Ackermann, T. Smejkal, J. Wencel-Delord, "Air-stable bis-cyclometallated iridium catalysts for ortho-directed C(sp2)–H borylation", Adv. Synth. Catal. 2024, in press. Abstract>
543) W. Wei, B. Wang, S. L. Homölle, J. Zhu, Y. Li, T. von Münchow, I. Maksso, L. Ackermann, "Photoelectrochemical Iron-Catalyzed C(sp3)/Si–H Borylation of Alkanes in a Position-Selective Manner", CCS Chem. 2024, in press. Abstract>
542) L. Wang', X. Huo', X. He, L. Ackermann, D. Wang, "Photoelectrochemical Nickel-Catalyzed Carboacylation/ Silanoylation of Alkenes with Unactivated C/Si–H Bonds", Green Chem. 2024, in press.' These authors contributed equally Abstract>
541) K. Zeng, N. K. Pandit, J. C. A. Oliveira, S. Dechert, L. Ackermann, K. Zhang, "Weak-coordination-auxiliary aminocatalysis enables directed [3 + 2] cyclization for 2-acylindolizines", Green Chem. 2024, in press. Abstract>
540) L. Guillemard, L. Ackermann, M. J. Johansson, "Late-stage meta-C–H alkylation of pharmaceuticals to modulate biological properties and expedite molecular optimisation in a single step", Nat. Commun. 2024, 15, 3349. Abstract>
539) Y-N. Ding, M-Z. Xu, Y-C. Huang, L. Ackermann, X. Kong, X-Y. Liu, Y-Min Liang, "Stereoselective assembly of C-oligosaccharides via modular difunctionalization of glycals", Nat. Commun. 2024, 15, 2794. Abstract>
538) Z-J. Zhang, M. M. Simon, S. Yu, S-W. Li, X. Chen, S. Cattani, X. Hong, L. Ackermann, "Nickel-Catalyzed Atroposelective C–H Alkylation Enabled by Bimetallic Catalysis with Air-Stable Heteroatom-Substituted Secondary Phosphine Oxide Preligands", J. Am. Chem. Soc. 2024, 146, 13, 9172–9180. Abstract>
537) A. M. Messinis, T. von Münchow, M. Surke, L. Ackermann, "Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents", Nat. Catal. 2024, 7, 273–284. Abstract>
536) L. Ackermann, "Special Issue on Electrochemically-Driven Organic Synthesis", (Editorial) Isr. J. Chem. 2024, 64, e2024000. Abstract>
535) J. Struwe, T. Oyama, F. Gallou, L. Ackermann, "Manganese(I)-Catalyzed C–H Allylation of Tryptophanes and their Oligopeptides on Water", Synlett 2024, 35, A-E. Abstract> (Special issue dedicated to Prof. Keith Fagnou )
534) T. von Münchow, N. K. Pandit, S. Dana, P. Boos, S. E. Peters, J. Boucat, Y.-R. Liu, A. Scheremetjew, L. Ackermann, "Nickel-electrocatalyzed enantioselective C–H activations for chemo-divergence" Research Square 2024, https://doi.org/10.21203/rs.3.rs-3760859/v1. Abstract>
533) Z. Lin, J. C. A. Oliveira, A. Scheremetjew, L. Ackermann, "Palladium-Catalyzed Electrooxidative Double C–H Arylation" J. Am. Chem. Soc. 2024, 146, 1, 228-239. Abstract>
532) Y. Zhao,' X. Li,' S. L. Homölle, B. Wang, L. Ackermann, "Electrochemical assembly of isoxazoles via a four-component domino reaction", Chem. Sci. 2024, 15, 1117-1122. ' These authors contributed equally. Abstract>
531) A. Zangarelli, B. Yuan, L. Ackermann, "Electrochemical C7-Indole Alkenylation via Rhodium Catalysis", Israel J. Chem. 2024, DOI: 10.1002/ijch.202300103. Abstract>
530) T. von Münchow, Y. Li, Z.-J. Zhang, P. Boos, L. Ackermann, "Carbon-Carbon Bond Formation by Asymmetric Iron- and Cobalt-Catalyzed Reactions" , in Comprehensive Chirality, 2nd edition (Ed.: Janine Cossy), Elsevier, 2024, in press.
529) J. Mo,' A. M. Messinis,' J. Li, S. Warratz, L. Ackermann, "Chelation-Assisted Iron-Catalyzed C–H Activations: Scope and Mechanism" Acc. Chem. Res. 2024. 57, 10–22 ' These authors contributed equally. Abstract> 
528) J. Wegener, G. Mitronova, L. ElShareif, C. Quentin, V. Belov, T. Pochechueva, G. Hasenfuß, L. Ackermann, S. Lehnart, "A dual-targeted drug inhibits cardiac Ryanodine Receptor Ca2+-leak but activates SERCA2a Ca2+-uptake", Life Sci. Alliance 2024, 7, e202302278. Abstract>
527) D. Antermite, S. D. Friis, J. R. Johansson, O. D. Putra, L. Ackermann, M. J. Johansson, "Late-stage synthesis of heterobifunctional molecules for PROTAC applications via ruthenium-catalysed C‒H amidation", Nature Commun. 2023, 14, 8222. Abstract>
526) Z. Cai, S. Trienes, K. Liu, L. Ackermann, Y. Zhang, "Radical Cascade Cyclization of 1,n-Enynes under Photo/Electrochemical Conditions", Org. Chem. Front. 2023, 10, 5735-5745. Abstract>
525) T. von Münchow, L. Ackermann, "Radical approach for enantioselective amination" Nature Synthesis 2023, 2, 1132–1133. Abstract>
524) Y. Wang, R. Zhao, L. Ackermann, "Electrochemical Syntheses of Polycyclic Aromatic Hydrocarbons (PAHs)" Adv. Mater. 2023, 2300760. Abstract>
523) E. Y. Lai, B. Yuan, L. Ackermann, M. J. Johansson, "Ruthenium-Catalyzed Aminocarbonylation with Isocyanates Through Weak Coordinating Groups", Chem. Eur. J. 2023, 28, e202302023. Abstract>
522) B.-S. Zhang,' W.-Y. Jia,' Y.-M.Wang, J. C. A. Oliveira, S.Warratz, Z.-Q.Zhang, X.-Y. Gou,Y.-M. Liang, X.-C. Wang, Z.-J. Quan, L. Ackermann, "Template Synthesis to Solve the Unreachable Ortho C–H Functionalization Reaction of Aryl Iodide" J. Org. Chem. 2023, 88, 16539–16546. ' These authors contributed equally. Abstract>
521) A. Luc, J. C.A. Oliveira, P. Boos, N. Jacob, L. Ackermann, J. Wencel-Delord, "Double cobalt-catalyzed atroposelective C–H activation: One-step synthesis of atropisomeric indoles bearing vicinal C–C and C–N diaxes", Chem. Catalysis 2023, 3, 100765. Abstract
520) B.-S. Zhang,' Y.-.i Yang,' J. C. A. Oliveira, Z.-Q. Zhang, S. Warratz, Y.-M. Wang, S.-X. Li, X.-C. Wang, X.-Y. Gou, Y.-M. Liang, Z.-J. Quan, L. Ackermann, "Combined C-H amination and intermolecular alkyne insertion for a three-component cyclization" Cell Rep. Phys. Sci. 2023, 4, 101550. ' These authors contributed equally. Abstract>
519) R. L. de Carvalho, E. B. T. Diogo, S. L. Homölle, S. Dana, E. N. da Silva Júnior, L. Ackermann, "The Crucial Role of Silver(I)-Salts as Additives on C–H Activation Reactions: Overall Analysis of their Versatility and Applicability" Chem. Soc. Rev. 2023, 6359-6378. Abstract>
518) R. Zhao,' M. Surke,' Z. Lin, A. Alsalme, L. Ackermann, "Site-selective electrochemical carboxylation of aromatic C(sp2)–H bonds with CO2", Curr. Res. Green Sustainable Chem. 2023, 7, 100377. ' These authors contributed equally. Abstract>
517) E. B. T. Diogo, F.G. Delolo, G. A. P. Graça, E.R. S. Paz, I. A. O. Bozzi, R. Diniz, J. P. Passos, T. Matencio, L. K. Soares, D. Alves, P. M. S. Costa, C. Pessoa, C. L. M. Pereira, L.Ackermann, E, N. da Silva Júnior, "Electrochemical Sulphenylation/Cyclization of Quinones: A Rapid, Green and Efficient Access to Cytotoxic Compounds" Eur. J. Org. Chem. 2023, 14, e202300506. Abstract>
516) Y. Wang,' S. Dana,' H. Long,' Y. Xu, Y. Li, N. Kaplaneris, L. Ackermann, "Electrochemical Late-Stage Functionalization" Chem. Rev. 2023, 123, 11269–11335. ' These authors contributed equally. Abstract>
515) J. Struwe, L. Ackermann, "Photoelectro-Catalyzed Undirected C‒H Trifluoromethylation of Arenes: Catalyst Evaluation and Scope" Faraday Discuss. 2023, 242, 79 - 86. Abstract>
514) W. Wei, S. L. Homölle, T. von Münchow, Y. Li, I. Maksso, L. Ackermann, "Photoelectrochemical Si−H and Ge−H Activation by Iron Catalysis" Cell Rep. Phys. Sci. 2023, 4, 101550. Abstract>
513) I. Maksso,' R. C. Samanta,' Y. Zhan, K. Zhang, S. Warratz, L. Ackermann, "Polymer Up-Cycling by Mangana-Electrocatalytic C(sp3)–H Azidation without Directing Groups" Chem. Sci. 2023, 14, 8109-8118. ' These authors contributed equally.Abstract>
512) S. L. Homölle,' M. Stangier,' E. Reyes, L. Ackermann, "Bifurcated Rhodaelectro-Catalyzed C–H Activation for the Synthesis of Pyrroles and Lactones" Precision Chem. 2023, 1, 382–387. ' These authors contributed equally. Abstract>
511) M. A. Brimble, L. Ackermann, Y.-M. Li , M. Raj, "Chemoselective Methods for Labeling and Modification of Peptides and Proteins" (Editorial) Org. Lett. 2023, 25, 6605–6606. Abstract>
510) Z. Lin,' U. Dhawa,' X. Hou,' M. Surke, B. Yuan, S.-W. Li, Y.-C. Liou, M. J. Johansson, L.-C. Xu, C.-H. Chao, X. Hong, L. Ackermann, Nature Commun. 2023, 14, 4224. Abstract>
Zhipeng Lin,' U. Dhawa,' B. Yuan, Y.-C. Liou, M. J. Johansson, L. Ackermann, "Electrocatalyzed Direct Arene Alkenylations without Directing Groups: Selective Late-Stage Drug Diversification" Research Square 2022, https://doi.org/10.21203/rs.3.rs-1607467/v1. ' These authors contributed equally. Abstract>
509) Y. Lin, T. von Münchow, L. Ackermann, "Cobaltaelectro-Catalyzed C–H Annulation with Allenes for Atropochiral and P-stereogenic Compounds: Late-stage Diversification and Continuous Flow Scale up" ChemRxiv 2023, DOI:10.26434/chemrxiv-2023-7g4z2. ACS Catal. 2023, 13, 9713–9723. Abstract>
508) S. Chen, B. Yuan, Y. Wang, L. Ackermann, "Ruthenium-Catalyzed Remote-Difunctionalization of Nonactivated Alkenes for Double meta-C(sp2)−H/C-6(sp3)−H Functionalization" Angew. Chem. Int. Ed. 2023, 62, e202301168. Abstract>
507) Z-J. Zhang, S.-W. L, J. C. A. Oliveira, Y. Li, X. Chen, S.-Q. Zhang, L.-C. Xu, T. Rogge, X. Hong, L. Ackermann, "Data-driven design of new chiral carboxylic acid for construction of indoles with C-central and C–N axial chirality via cobalt catalysis" Nature Commun. 2023, 14, 3149. Abstract>
506) L.-C. Xu, J. Frey, X. Hou, S.-Q. Zhang, Y.-Y. Li, J. C. A. Oliveira, S.-W. Li, L. Ackermann, X. Hong, "Enantioselectivity prediction of pallada-electrocatalysed C–H activation using transition state knowledge in machine learning" Nature Synthesis 2023, 2, 321–330. Abstract>
505) M. Surke, R. Zhao, L. Ackermann, "Electrolyser design controls position-divergent C–H carboxylation" Sci. China Chem. 2023, 66, 1549–1550. Abstract>
504) T. Oyama, L. Mendive-Tapia,, V. Cowell, A. Kopp, M. Vendrell, L. Ackermann, "Late-Stage Peptide Labeling with Near-Infrared Fluorogenic Nitrobenzodiazoles by Manganese-Catalyzed C–H Activation" Chem. Sci. 2023, 14, 5728-5733. Abstract>
503) Y. Zhang, C. Zhao, C. Ma, Z. Cai, S. Trienes, L. Ackermann, "Photocatalytic C–C Cleavage of Methylenecyclobutanes for γ,δ-Unsaturated Aldehydes by Strain Release" Angew. Chem. Int. Ed. 2023, 62, e202300166. Abstract>
502) Y. Li, S. Dana, L. Ackermann, "Recent advances in organic electrochemical functionalizations for specialty chemicals" Curr. Opin. Electrochem. 2023, 39, 101312. Abstract>
501) X. Chen, H. C. Gülen, J. Wu, Z.-J. Zhang, X. Hong, L. Ackermann, "Close-Shell Reductive Elimination versus Open-Shell Radical Coupling for Site-Selective Ruthenium-Catalyzed C–H Activations by Computation and Experiments" Angew. Chem. Int. Ed. 2023, 62, e202302021. Abstract>
500) T. von Münchow, S. Dana, Y. Xu, B. Yuan, L. Ackermann, "Enantioselective electrochemical cobalt-catalyzed aryl C–H activation reactions" Science 2023, 379, 1036–1042. Abstract> highlighted on c&en> , Synform
T. von Münchow, S. Dana, Y. Xu, B. Yuan, L. Ackermann, "Enantioselective cobaltaelectro-catalyzed C–H activations enabled by hydrogen evolution" ChemRxiv 2023, DOI:10.26434/chemrxiv-2023-dzw3d.
499) D. Wang, B. Yuan, J. Xu, L. Ackermann, "Electrochemical Rearrangement for Remote Functionalizations of Unactivated Alkenes" Chem. Eur. J. 2023, 28, e202300600. Abstract>
498) B. Yuan. J. C. A. Oliveira, L. Ackermann, "Understanding and Describing London Dispersion Effects in Transition Metal-Catalyzed C–H Activations" Synlett 2023, 34,1098-1112. Abstract>
497) J. Wu, W. Wei, J. Pöhlmann, R. Purushothaman, L. Ackermann, "Domino meta-C−H Ethyl Glycosylation by Ruthenium(II/III) Catalysis: Modular Assembly of meta-C-Alkyl Glycosides" Angew. Chem. Int. Ed. 2023, 62, e202219319. Abstract>
496) J.-B. Liu, X.-J. Liu, J. C. A. Oliveira, D.-Z. Chen, L. Ackermann, "Cobalt-catalyzed radical-mediated carbon-carbon scission via a radical-type migratory insertion" Chem. Sci. 2023, 14, 3352-3362. Abstract>
495) Y. Zhang, Z. Cai, C. Zhao, H. Zheng, L. Ackermann, "Electrosynthesis of Bridged or Fused Sulfonamides through Complex Radical Cascade Reactions: Divergence in Medium-Sized Ring Formation" Chem. Sci. 2023, 14, 3541-3547. Abstract>
494) K. Zeng, R. Mei, S. Dechert, L. Ackermann, K. Zhang, "A recyclable stereoauxiliary aminocatalyzed strategy for one-pot synthesis of indolizine-2-carbaldehydes" Commun. Chem. 2023, 6, 40. Abstract>
493) L. Ackermann, S. Lin, "Special Collection on Organic Electrocatalysis" Eur. J. Org. Chem. 2023, e202300214. Abstract>
492) N. Kaplaneris, A. Puet, F. Kallert, J. Pöhlmann, L. Ackermann, "Late-stage C–H Functionalization of Tryptophan-containing Peptides with Thianthrenium Salts: Conjugation and Ligation" Angew. Chem. Int. Ed. 2023, 62, e20221666. Abstract>
491) J. Struwe, L. Ackermann, F. Gallou, "Recent Progress in Copper-free Sonogashira-Hagihara Cross-Couplings in Water" Chem. Catal. 2023, 3, 100485. Abstract>
490) S. Cattani, A. Secchi, L. Ackermann, G. Cera, "Triazole-enabled, iron-catalysed linear/branched selective C−H alkylations with alkenes" Org. Biomol. Chem. 2023, 21, 1264-1269. Abstract>
489) Y. Zhang, Z. Cai, S. Warratz, C. Ma, L. Ackermann, "Recent Advances in Electrooxidative Radical Transformations of Alkynes" Sci. China Chem. 2023, 66, 703-724. Abstract>
488) S.-Q. Zhang, L.-C. Xu, S.-W. Li, J. C. A. Oliveira, X. Li, L. Ackermann, X. Hong, "Bridging Chemical Knowledge and Machine Learning for Performance Prediction of Organic Synthesis" Chem. Eur. J. 2023, 28, e202202834. Abstract>
487) T. Goldhardt, M. Edelmann, T. de Oliveira, A. Bleckmann, K. Menck, L. Ackermann, T. Rogge, T. Beissbarth, M. Ghadimi, L.-C. Conradi, Oncology Research and Treatment 2022, 45, 6-285. Abstract>
486) J. Wegener, G. Mitronova, C. Quentin, G. Hasenfuss, L. Ackermann, S. Lehnart, "Development and analysis of novel small-molecule RyR2 compounds on RyR2 and SERCA2a activity in living permeabilized cardiomyocytes" J. Mol. Cell. Cardiol., 2022, 173, 88. Abstract>
485) Y. Li, Y.-C. Liou, J. C. A. Oliveira, L. Ackermann, "Ruthenium(II)/Imidazolidine Carboxylic Acid-Catalyzed C−H Alkylation for Central and Axial Double Enantio-Induction" Angew. Chem. Int. Ed. 2022, 61, e202212595. Abstract>
484) R. Zhao, Z. Lin, I. Maksso, J. Struwe, L. Ackermann, "Electrochemical Cross-Electrophile-Coupling for Transition-Metal-Free Allylic Carboxylation with Ambient CO2" ChemElectroChem 2022, 9, e202200989. Abstract>
483) J. Wu, N. Kaplaneris, J. Pöhlmann, T. Michiyuki, B. Yuan, L. Ackermann, "Remote C–H Glycosylation by Ruthenium(II) Catalysis: Modular Assembly of meta-C-Aryl Glycosides" Angew. Chem. Int. Ed. 2022, 61, e202208620. Abstract>
482) J. C. A. Oliveira, J. Frey S.-Q. Zhang, L.-C. Xu, X. Li, S.‑W. Li, X. Hong, L. Ackermann, "When machine learning meets molecular synthesis" Trends Chem. 2022, 4, 863-885. Abstract>
481) M. Stangier, A. Scheremetjew, L. Ackermann, "Chemo- and Site-Selective Electrooxidative Alkane Fluorination by C(sp3)–H Cleavage" Chem. Eur. J. 2022, 28, e202201654. Abstract>
480) A. Berger, T. Knak, A.-L. Kiffe-Delf, K. Mudrovcic, V. Singh, M. Njoroge, B. B. Burckhardt, M. Gopalswamy, B. Lungerich, L. Ackermann, H. Gohlke, K. Chibale, R. Kalscheuer, T. Kurz, "Total Synthesis of the Anti-mycobacterial Natural Product Chlorflavonin and Analogs via a Late-stage Ruthenium(II)-Catalyzed ortho-C(sp2)-H-Hydroxylation" Pharmaceuticals 2022, 15, 984. https://doi.org/10.3390/ph15080984. Special Issue on C–H Functionalization Chemistry: Applications in Drug Synthesis. Abstract>
479) D. Wang, L. Ackermann, "Three-Component Carboacylation of Alkenes via Cooperative Nickelaphotoredox Catalysis" Chem. Sci. 2022, 13, 7256-7263. Abstract>
478) Y. Wang, S. Chen, X. Chen, A. Zangarelli, L. Ackermann, "Photo-Induced Ruthenium-Catalyzed Double Remote C(sp2)−H/ C(sp3)−H Functionalizations by Radical Relay" Angew. Chem. Int. Ed. 2022, 61, e202205562. Abstract>
477) F. Wang, Y. Chen, L. Ackermann, S.-Y. Wang, "Efficient Preparation of Unsymmetrical Alkyl-Aryl Tellurides by Nickel-Catalyzed Reductive Coupling Strategy" Org. Chem. Front. 2022, 9, 3199-3203. Abstract>
476) Y. Yuan, J. Zhu, Z. Yang, S.-F. Ni, Q. Huang, L. Ackermann, "Scalable Rhodaelectro-Catalyzed Expedient Access to Seven-membered Azepino[3,2,1-hi]indoles via [5+2] C-H/N-H Annulation" CCS Chem 2022, 4, 1858-1870. Abstract>
475) F. Wang, Y. Chen, W. Rao, L. Ackermann, S.-Y. Wang, "Efficient preparation of unsymmetrical disulfides by nickel-catalyzed reductive coupling strategy" Nature Commun. 2022, 13, 2588. Abstract>
474) N. Kaplaneris, M. Vilches-Herrera, J. Wu, L. Ackermann, "Sustainable Ruthenium(II)-Catalyzed C–H Activations in and on H2O"ACS Sustain. Chem. Eng. 2022, 10, 6871-6888. Abstract>
473) B. B. Jei, L. Yang, L. Ackermann, "Selective Labeling of Peptides with o-Carboranes via Manganese(I)-Catalyzed C-H Activation" Chem. Eur. J. 2022, 28, e202200811. Abstract>
472) Y. Zhang, C. Ma, Z. Cai, J Struwe, S. Chen, J. Xu, S. Li, W. Zeng, L. Ackermann, "Electrooxidative tricyclic 6-7-6 fused-system domino assembly to allocolchicines by a removable radical strategy" Green Chem. 2022, 24, 3697-3703. Abstract>
471) A. M. Messinis, J. C. A. Oliveira, A. C. Stückl, L. Ackermann, "Cyclometallated Iron(II) Alkoxides in Iron-Catalyzed C–H Activations by Weak O-Carbonyl Chelation" ACS Catal. 2022, 12, 4947–4960. Abstract>
470) L. Capdevila, J. Sala, L. Ackermann, X. Ribas, "Nickel-catalyzed Csp2-OMe functionalization for chemoselective aromatic homologation en route to nanographenes" Chem. Eur. J. 2022, 28, e202200625. Abstract>
469) Y. Li, Y.-C. Liou, X. Chen, L. Ackermann, "Thioether-enabled palladium-catalyzed atroposelective C–H olefination for N−C and C−C axial chirality" Chem. Sci. 2022, 13, 4088-4094. Abstract>
468) B. Sadowski, B. Yuan, Z. Lin, L. Ackermann, "Rhodaelectro-catalyzed peri-Selective Direct Alkenylations with Weak O-Coordination Enabled by the Hydrogen Evolution Reaction (HER)" Angew. Chem. Int. Ed. 2022, 61, e202117188. Abstract>
467) L. Yang, Z.-J. Zhang, B. B. Jei, L. Ackermann, "Electrochemical Cage Activation of Carboranes"Angew. Chem. Int. Ed. 2022, 61, e202200323. Abstract>
466) L. Herrmann, I. A. Yaremenko, A. Çapcı, J. Struwe, D. Tailor, A. Dheeraj, J. Hodek, Y. Y. Belyakova, P. Radulov, J. Weber, S. V. Malhotra, A. O. Terent'ev, L. Ackermann, S. B. Tsogoeva, "Synthesis and In Vitro Study of Artemisinin/Synthetic Peroxide Based Hybrid Compounds against SARS-CoV-2 and Cancer" ChemMedChem 2022, 17, e202200005. Abstract>
465) X. Hou,' N. Kaplaneris,' B. Yuan, J. Frey, T. Ohyama, A. Messinis, L. Ackermann, "Ruthenaelectro-Catalyzed C–H Acyloxylation for Late-Stage Tyrosine and Oligopeptide Diversification" Chem. Sci. 2022, 13, 3461-3467. ' These authors contributed equally. Abstract>
464) Y. Wang, H. Simon, X. Chen, Z. Lin, S. Chen, L. Ackermann, "Distal Ruthenaelectro-Catalyzed meta-C−H Bromination with Aqueous HBr" Angew. Chem. Int. Ed. 2022, 61, e202201595. Abstract>
463) J. Frey,' X. Hou,' L. Ackermann, "Atropoenantioselective Palladaelectro-Catalyzed Anilide C–H Olefinations Viable with Natural Sunlight as Sustainable Power Source" Chem. Sci. 2022, 13, 2729-2734. ' These authors contributed equally. Abstract>
462) W. Wei, A. Scheremetjew, L. Ackermann, "Electrooxidative Palladium- and Enantioselective Rhodium-Catalyzed [3+2] Spiroannulations" Chem. Sci. 2022, 13, 2783-2788. Abstract>
461) L. Mendive-Tapia, D. Mendive-Tapia, C. Zhao, D. Gordon, S. Benson, M. J. Bromley, W. Wang, J. Wu, A. Kopp, L. Ackermann, M. Vendrell, "Rational Design of Phe-BODIPY Amino Acids as Fluorogenic Building Blocks for Peptide-based Detection of Urinary Tract Candida Infections" Angew. Chem. Int. Ed. 2022, 61, e202117218. Abstract>
460) U. Dhawa, T. Wdowik, L. Ackermann, "Asymmetric C–H Functionalization of C(sp2)–H bond", in Catalytic Asymmetric Synthesis (Eds.: T. Akiyama, I. Ojima), Wiley-VCH, Weinheim, 2022, 387-428. Abstract>
459) T. Rogge, T. Müller, H. Simon, X. Hou, S. Wagschal, D. Broggini, L. Ackermann, "Triazole-Enabled Ruthenium(II)carboxylate-Catalyzed C–H Arylation with Electron-deficient Aryl Halides" Synlett 2022, 33, 346–350. Abstract> Special Cluster on Late-Stage Functionalization
458) J. Wu, A. Kopp, L. Ackermann, "Synthesis of C-Oligosaccharides through Versatile C(sp3)–H Glycosylation of Glycosides" Angew. Chem. Int. Ed. 2022, 61, e202114993. Abstract>
457) N. Jacob, Y. Zaid, J. C. A. Oliveira, Lutz Ackermann, J. Wencel-Delord, "Cobalt-Catalyzed Enantioselective C−H Arylation of Indoles" J. Am. Chem. Soc. 2022, 144, 798–806. Abstract>
456) N. Kaplaneris, L. Ackermann, "Earth-abundant 3d transition metals on the rise in catalysis" Beilstein J. Org. Chem. 2022, 18, 86-88. Abstract>
455) K. Kuciński, H. Simon, L. Ackermann, "Rhodaelectro-Catalyzed C–H Methylation and Paired Electrocatalyzed C–H Ethylation and Propylation" Chem. Eur. J. 2022, 28, e202103837. Abstract>
454) I. Choi, A. M. Messinis, X. Hou, L. Ackermann, "Strategy for Site- and Chemoselective C–H Alkenylation through Osmaelectrooxidative Catalysis" Angew. Chem. Int. Ed. 2021, 60, 27005-27012. Abstract> (Selected as hot paper)
453) Y. Zhang, Z. Cai, J. Struwe, C. Ma, W. Zeng,X. Liao, M. Xu, L. Ackermann, "Dibenzocycloheptanones construction through a removable P–centered radical: Synthesis of allocolchicine analogues" Chem. Sci. 2021, 12, 15727-15732. Abstract>
452) L. Ackermann (Ed.), Science of Synthesis: Electrochemistry in Organic Synthesis, Thieme: Stuttgart, 2021, 573 pages. Abstract>
451) L. Ackermann, "Introduction" In Science of Synthesis: Electrochemistry in Organic Synthesis, Ackermann, L., Ed.; Thieme: Stuttgart, 2021, 1-2. DOI: 10.1055/sos-SD-236-00001 Abstract>
450) A. Scheremetjew, T. H. Meyer, Z. Lin, L. Massignan, L. Ackermann, "Fundamental Principles of Organic Electrochemistry" In Science of Synthesis: Electrochemistry in Organic Synthesis, Ackermann, L., Ed.; Thieme: Stuttgart, 2021, 3-32. DOI: 10.1055/sos-SD-236-00002 Abstract>
449) U. Dhawa, T. Wdowik, X. Hou, B.Yuan, J. C. A. Oliveira, L. Ackermann, "Enantioselective Palladaelectro-Catalyzed C–H Olefinations and Allylations for N–C Axial Chirality" Chem. Sci. 2021, 12, 14182-14188. Abstract>
448) L. Yang, B. B. Jei, A. Scheremetjew, B. Yuan, C. Stückl, L. Ackermann, "Electrooxidative o-Carborane Chalcogenations Without Directing Groups: Cage Activation by Copper Catalysis at Room Temperature" Chem. Sci. 2021, 12, 12971-12976. Abstract>
447) P. Hauk, J. Wencel-Delord, L. Ackermann, P. Walde, F. Gallou, "Organic Synthesis in Aqueous Multiphase Systems - Challenges and Opportunities ahead of Us" Curr. Opin. Colloid Interface Sci. 2021,101506. Abstract>
446) J. Struwe, K. Korvorapun, A. Zangarelli, L. Ackermann, "Photo-Induced Ruthenium-Catalyzed C‒H Benzylations and Allylations at Room Temperature" Chem. Eur. J. 2021, 27, 16237-16241. Abstract>
445) L. Massignan, C. Zhu, X. Hou, J. C. A. Oliveira, A. Salamé, L. Ackermann, "Manganaelectro-Catalyzed Azine C–H Arylations and C–H Alkylations by Assistance of Weakly-Coordinating Amides" ACS Catal. 2021, 11, 11639–11649. Abstract>
444) B. Zhao, T. Rogge, L. Ackermann, Z. Shi, "Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation" Chem. Soc. Rev. 2021, 50, 8903-8953. Abstract>
443) M. Stangier, A. Messinis, J. C. A. Oliveira, H. Yu, L. Ackermann, "Rhodaelectro-catalyzed access to chromones via formyl C–H activation towards peptide electro-labeling" Nature Commun. 2021, 12, 4736. Abstract>
442) L. Guillemard, N. Kaplaneris, L. Ackermann, M. Johansson, "Late-stage C–H functionalization offers new opportunities in drug discovery" Nature Rev. Chem. 2021, 5, 522-545. Abstract>
441) Y. Zhang, C. Ma, J. Struwe, J. Feng, G. Zhu, L. Ackermann, "Electrooxidative Dearomatization of Biaryls: Synthesis of Tri- and Difluoromethylated Spiro[5.5]trienones" Chem. Sci. 2021, 12, 10092-10096. Abstract>
440) F. Xiong, C. Yang, W. Ma, L. Gu, R. Mei, L. Ackermann, "Copper-mediated oxidative C−H/N−H activations with alkynes by removable hydrazides" Beilstein J. Org. Chem. 2021, 17, 1591-1599. Abstract>
439) I. Choi, Z. Shen, E. Ronge, V. Karius, C. Jooss, L. Ackermann, "Reusable Manganese Catalyst for Site-Selective Pyridine C–H Arylations and Alkylations" Chem. Eur. J. 2021, 27, 12737-12741. Abstract>
438) T. Rogge, N. Kaplaneris, N. Chatani, J. Kim, S. Chang, B. Punji, L. L. Schafer, D. G. Musaev, J. Wencel-Delord, C. A. Roberts, R. Sarpong, Z. E. Wilson, M. A. Brimble, M. J. Johansson, L. Ackermann, "C–H Activation" Nature Rev. Methods Primer 2021, 1, 43. Abstract>
437) S.-K. Zhang, A. Del Vecchio, R. Kuniyil, A. M. Messinis, Z. Lin, L. Ackermann, "Electrocatalytic C–H phosphorylation through nickel(III/IV/II) catalysis" Chem 2021, 7, 1379-1392. Abstract>
436) U. Dhawa, N. Kaplaneris, L. Ackermann, "Green Strategies for Transition Metal-Catalyzed C−H Activation in Molecular Syntheses" Org. Chem. Front. 2021, 8, 4886-4913. Abstract>
435) Y. Wang, Z. Lin, J. C. A. Oliveira, L. Ackermann, "Electro-Oxidative Intermolecular Allylic C(sp3)−H Aminations" J. Org. Chem. 2021, 86, 15935–15945. Electrochemistry in Synthetic Organic Chemistry special issue. Abstract>
434) T. H. Meyer, L. Ackermann, "Chemistry with Potential: Present Challenges and Emerging Trends in Organic Electrocatalysis" Aldrichimica Acta 2021, 54, 29-31. Abstract>
433) I. Choi, J. Struwe, L. Ackermann, "C–H Activation by Immobilized Heterogeneous Photocatalysts" Photochem. & Photobiol. Sci. 2021, 20, 1563–1572. Abstract>
432) R. N. Lima, J. A. C. Delgado, D. I. Bernardi, R. G. S. Berlinck, N. Kaplaneris, L. Ackermann, M. W. Paixão, "Post-Synthetic Functionalization of Tryptophan Protected Peptides Sequences through Indole (C-2) Photocatalytic Alkylation" Chem. Commun. 2021, 57, 5758-5761. Abstract> Chemical Communications Hot Article
431) W. Wei, H. Yu, A. Zangarelli, L. Ackermann, "Deaminative meta-C–H Alkylation by Ruthenium(II)Catalysis" Chem. Sci. 2021, 12, 8073-8078. Abstract> Themed collection 2021 Chemical Science Hot Article Collection
430) N. Kaplaneris, J. Son, L. Mendive-Tapia, A. Kopp, N. D. Barth, I. Maksso, M. Vendrell, L. Ackermann,"Chemodivergent manganese-catalyzed C–H activation: modular synthesis of fluorogenic probes" Nature Commun. 2021, 11, 3389. Abstract>
429) R. C. Samanta, L. Ackermann, "Evolution of Earth-Abundant 3 d-Metallaelectro-Catalyzed C−H Activation: From Chelation-Assistance to C−H Functionalization without Directing Groups" Chem. Rec. 2021, 2430-2441. Abstract>
428) K. Korvorapun, R. C. Samanta, T. Rogge, L. Ackermann, "Remote C–H Functionalizations by Ruthenium Catalysis" Synthesis 2021, 53, 2911-2934. Abstract> Special issue dedicated to Prof. Shinji Murai.
427) S. B. Tsogoeva, G. Dong, L. Ackermann, "The Catalysis of Ring Synthesis" ChemCatChem 2021, 13, 2962-2964. Abstract>
426) X. Tan,' L. Massignan,' X. Hou, J. Frey, J. C. A. Oliveira, M. Nasiha Hussain, L. Ackermann, "Rhoda-Electrocatalyzed Bimetallic C–H Oxygenation by Weak O-Coordination" Angew. Chem. Int. Ed. 2021, 60, 13264-13270. ' These authors contributed equally. Abstract>
425) N. Kaplaneris, F. Kaltenhӓuser, G. Sirvinskaite, S. Fan, T. De Oliveira, L.-C. Conradi, L. Ackermann, "Late-Stage Stitching Enabled by Manganese-Catalyzed C–H Activation: Peptide Ligation and Access to Cyclopeptides" Sci. Adv. 2021, 9, eabe6202. Abstract>
424) U. Dhawa,' R. Connon,' J. C. A. Oliveira,' R. Steinbock, L. Ackermann, "Enantioselective Ruthenium-Catalyzed C–H Alkylations by a Chiral Carboxylic Acid with Attractive Dispersive Interactions" Org. Lett. 2021, 23, 2760–2765. ' These authors contributed equally. Abstract>
423) Y. Weng, H. Chen, N. Li, L. Yang, L. Ackermann, "Electrooxidative Metal-Free Cyclization of 4-Arylaminocoumarins Employing DMF as C1-Source" Adv. Synth. Catal. 2021, 363, 2773-2777. Abstract>
422) I. Choi, V. Müller, L. Ackermann, "Ruthenium(II)-Carboxylate-Catalyzed C4/C6–H Dual Alkylations of Indoles" Tetrahedron. Lett. 2021, 69, 153064. Special issue for Tetrahedron Young Investigator Award to Prof. Guangbin Dong. Abstract>
421) T. B. Gontijo, R. L. de Carvalho, L. Dantas-Pereira, R. F. S. Menna-Barreto, L. Ackermann, E. N. da Silva Júnior, "Ruthenium(II)- and Palladium(II)-Catalyzed Position-Divergent C–H Oxygenations of Arylated Quinones: Identification of Hydroxylated Quinonoid Compounds with Potent Trypanocidal Activity" Bioorg. Med. Chem. 2021, 116164. Abstract>
420) Y. Wang, J. C. A. Oliveira, Z. Lin, L. Ackermann, "Electrooxidative Rhodium‐Catalyzed [5 + 2] Annulations via C–H/O–H Activations" Angew. Chem. Int. Ed. 2021, 60, 6419-6424. Abstract>
419) Z. Shen, I. Maksso, R. Kuniyil, T. Rogge, L. Ackermann, "Rhodaelectro-catalyzed Chemo-Divergent C–H Activations with Alkylidenecyclopropanes for Selective Cyclopropylations" Chem. Commun. 2021, 57, 3668-3671. Abstract>
418) C. Zhu,' N. W. J. Ang,' T. H. Meyer, Y. Qiu, L. Ackermann, "Organic Electrochemistry: Molecular Syntheses with Potential" ACS Cent. Sci. 2021, 7, 415-431. Abstract>
417) Z. Ruan, Z. Huang, K. Kucinski, L. Ackermann, "Electrochemical Fluoroalkylation", in Science of Synthesis: Electrochemistry in Organic Synthesis (Ed.: L. Ackermann), Thieme, Stuttgart, 2021, 207-256.
416) R. Mei, R. C. Samanta, U. Dhawa, W. Ma, L. Ackermann, "Electrochemical Cobalt-Catalyzed C−H Activations with Potential", in The Chemistry of Organocobalt Chemistry (Eds.: C. Gosmini, I. Marek), Wiley-VCH, Weinheim, 2021, in press.
415) J. C. A. Oliveira, U. Dhawa, L. Ackermann, "Insights into the Mechanism of Low-Valent Cobalt-Catalyzed C–H Activation" ACS Catal. 2021, 11, 1505-1515. Abstract>
414) T. H. Meyer,' R. C. Samanta,' A. Del Vecchio, L. Ackermann, "Mangana(III/IV)electro-Catalyzed C(sp3)–H Azidation" Chem. Sci. 2021, 12, 2890-2897. ' These authors contributed equally. Abstract>
413) X. Tan, X. Hou, T. Rogge, L. Ackermann, "Ruthenaelectro-Catalyzed Domino Three-Component Alkyne Annulation Expedient Isoquinoline Assembly" Angew. Chem. Int. Ed. 2021, 60, 4619-4624. Abstract> (highlighted on Synfacts 2021, 17, 287)
412) T. De Oliveira, T. Goldhardt, M. Edelmann, T. Rogge, K. Rauch, N. Dobrinov Kyuchukov, K. Menck, A. Bleckmann, J. Kalucka, S. Khan, J. Gaedcke, M. Haubrock, T. Beissbarth, H. Bohnenberger, M. Planque, S.-M. Fendt, L. Ackermann, M. Ghadimi, L.-C. Conradi, "Effects of the novel PFKFB3 inhibitor KAN0438757 on colorectal cancer cells and its systemic toxicity evaluation in vivo" Cancers 2021, 13, 1011. Abstract>
411) X. Fang, Y. Tan, L. Gu, L. Ackermann, W. Ma, "para‐Selective Palladium‐Catalyzed C–H Difluoroalkylation by Oxazolidinones Weak Assistance" ChemCatChem 2021,13, 1738-1742. Abstract>
410) L. Yang, J. Frey, L. Ackermann, "Nickela-electrocatalyzed sulfide and phosphine oxygenations with water" Sci. China Chem. 2021, 64, 873-874 . Abstract>
409) J. Mo,' A. M. Messinis,' J. C. A. Oliveira, S. Demeshko, F. Meyer, L. Ackermann, "Iron-Catalyzed Triazole-Enabled C–H Activation with Bicyclopropylidenes" ACS Catal. 2021, 11, 1053-1064. ' These authors contributed equally. Abstract>
408) L. Yang,' B. B. Jei,' A. Scheremetjew, R. Kuniyil, L. Ackermann, "Electrochemical B–H Nitrogenation: Access to Amino Acid and BODIPY-Labeled nido-Carboranes" Angew. Chem. Int. Ed. 2021, 60, 1482-1487. ' These authors contributed equally. Abstract>
407) N. W. J. Ang, L. Ackermann, "Electro-Reductive Nickel-Catalyzed Thiolation: Efficient Cross-Electrophile Coupling for C–S Formation" Chem. Eur. J. 2021, 27, 4883-4887. Abstract>
406) Y. Zhang, Z. Lin, L. Ackermann, "Electrochemical C–H Amidation of Heteroarenes with N-Alkyl Sulfonamides in Aqueous Medium" Chem. Eur. J. 2021, 27, 242-246. Abstract>
405) R. Mei, C. Yang, F. Xiong, M. Mao, H. Li, J. Sun, L. Zou, W. Ma, L. Ackermann, "Access to 10-Phenanthrenols via Electrochemical C−H/C−H Arylation" Adv. Synth. Catal. 2021, 363, 1120-1125. Abstract>
404) Y. Kuninobu, S. Sueki, N. Kaplaneris, L. Ackermann, "Manganese Catalysis", in Catalysis with Earth-Abundant Elements (Eds.: S. Thomas, U. Schneider), RSC books, 2021, in press. Abstract>
403) K. Korvorapun, R. C. Samanta, T. Rogge, L. Ackermann, "Ruthenium-Catalyzed Remote C–H Functionalizations", in Remote C-H bond Functionalizations (Eds.: D. Maiti, S. Guin), Wiley-VCH, Weinheim, 2021, 137-165. Abstract>
402) J.-B. Liu, X. Wang, A. Messinis, X.-J. Liu, R. Kuniyil, D.-Z. Chen, L. Ackermann, "Understanding the unique reactivity patterns of nickel/JoSPOphos manifold in the Nickel-catalyzed enantioselective C–H cyclization of imidazoles" Chem. Sci. 2021, 12, 718-729. Abstract>
401) W. Wang,' J. Wu,' R. Kuniyil, A. Kopp, R. N. Lima, L. Ackermann, "Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation" Chem 2020, 6, 3428-3439. ' These authors contributed equally. Abstract>
400) T. H. Meyer, I. Choi, C. Tian, L. Ackermann, "Power the Future – How Can Electrochemistry Make a Difference in Organic Synthesis?" Chem 2020, 6, 2484-2496. Abstract>
399) T. Rogge, J. C. A. Oliveira, R. Kuniyil, L. Hu, L. Ackermann, "Reactivity-Controlling Factors in Carboxylate-Assisted C–H Activation under 4d and 3d Transition Metal Catalysis" ACS Catal. 2020, 10, 10551-10558. Abstract>
398) L. Ackermann, S.-L. You, M. Oestreich, S. Meng, D. MacFarlane, Y. Yin, "Seeds for the Future: Growing Chemistry Trends; Metalla-Electrocatalysis for Full Resource Economy" Trends Chem 2020, 2, 275-277. Abstract>
397) Z. Xu, Y. Wang, Y. Zheng, Z. Huang, L. Ackermann, Z. Ruan,Manganese- and Rhenium-Catalyzed C‒H Enaminylation: Expedient Access to Novel Indole-purine Hybrids with Anti-Tumor Bioactivitiess"Org. Chem. Front. 2020, 7, 3709-3714. Abstract>
396) I. Choi, V. Müller, Y. Wang, K. Xue, R. Kuniyil, L. B. Andreas, V. Karius, J. G. Alauzun, L. Ackermann, "Recyclable Ruthenium Catalyst for Distal meta-C–H Activation" Chem. Eur. J. 2020, 26, 15290-15297. Abstract>
395) Y. Weng, X. Dinga, J. C. A. Oliveira, X. Xua, N. Kaplanerisb, M. Zhua, H. Chena, Z. Chen, L. Ackermann, "Peptide Late-Stage C(sp3)−H Arylation By Native Asparagine Assistance Without Exogenous Directing Group" Chem. Sci. 2020, 11, 9290-9295. Abstract>
394) V. Müller, D. Ghorai, L. Capdevila, A. M. Messinis, X. Ribas, L. Ackermann, "C–F Activation for C(sp2)–C(sp3) Cross-Coupling by a SPO-Nickel Complex" Org. Lett. 2020, 22, 7034-7040. Abstract>
393) K. Korvorapun,' M. Moselage,' J. Struwe, T. Rogge, A. M. Messinis, L. Ackermann, "Regiodivergent C–H and Decarboxylative Alkylation by Ruthenium Catalysis: ortho versus meta Position-Selectivity" Angew. Chem. Int. Ed. 2020, 59, 18795-18803. Abstract> ' These authors contributed equally.
392) R. C. Samanta, T. H. Meyer, I. Siewert, L. Ackermann, "Renewable Resources for Sustainable Metallaelectro-Catalysed C–H Activation" Chem. Sci. 2020, 11, 8657-8670. Abstract>
391) M. Wild, F. Hahn, B. Grau, L. Herrmann, A. Niesar, M. Schütz, M. M. Lorion, L. Ackermann, S. B. Tsogoeva, M. Marschall, "The artemisinin-derived autofluorescent compound BG95 exerts strong anticytomegaloviral activity based on a mitochondrial targeting mechanism"Int. J. Mol. Sci. 2020, 5578. Abstract>
390) H. Wang,' N. Kaplaneris,' L. Ackermann, "Allenes in Manganese(I)-Catalyzed C–C Activation and A Strategy for Cascade Ring-Expansion" Cell Rep. Phys. Sci. 2020, 1, 100178. ' These authors contributed equally. Abstract>
389) K. Korvorapun,' J. Struwe,' R. Kuniyil, A. Zangarelli, A. Casnati, M. Waeterschoot, L. Ackermann, "Photo-Induced Ruthenium-Catalyzed C–H Arylation at Ambient Temperature" Angew. Chem. Int. Ed. 2020, 59, 18103-18109. Abstract> ' These authors contributed equally.
388) A. M. Messinis,' L. H. Finger,' L. Hu, L. Ackermann, "Allenes for Versatile Iron-Catalyzed C–H Activation by Weak O-Coordination: Mechanistic Insights by Kinetics, Intermediate Isolation and Computation" J. Am. Chem. Soc. 2020, 142, 13102-13111. Abstract> ' These authors contributed equally.
387) Y. Qiu,' C. Zhu,' M. Stangier, J. Struwe, L. Ackermann, "Rhodaelectro-Catalyzed C–H and C–C Activation" CCS Chem. 2020, 2, 1529-1552. ' These authors contributed equally. Abstract>
386) Q. Bu,' R. Kuniyil,' S. Zhigao, E. Gońka, L. Ackermann, "Insights into Ruthenium(II/IV)-Catalyzed Distal C–H Oxygenation by Weak Coordination" Chem. Eur. J. 2020, 26, 16450-16454. Abstract> ' These authors contributed equally.
385) I. Choi, A. M. Messinis, L. Ackermann, "C7‐Indole Amidations and Alkenylations by Ruthenium(II) Catalysis" Angew. Chem. Int. Ed. 2020, 59, 12534-12540. Abstract>
384) S. D. Friis, M. J. Johansson, L. Ackermann, "Cobalt-catalysed C–H methylation for late-stage drug diversification" Nature Chem. 2020, 12, 511–519. Abstract>
383) U. Dhawa, C. Tian, W. Li, L. Ackermann, "Cobaltaelectro-Catalyzed C–H Allylation with Unactivated Alkenes" ACS Catal. 2020, 10, 6457–6462. Abstract>
382) A. Çapcı, M. M. Lorion, C. Mai, F. Hahn, J. Hodek, C. Wangen, J. Weber, M. Marschall, L. Ackermann, S. B. Tsogoeva, "(Iso)Quinoline-Artemisinin Hybrids via Click Chemistry: Highly Potent Agents against Viruses" Chem. Eur. J. 2020, 26, 12019-12026. Abstract>
381) P. Gandeepan, L. H. Finger, T. H. Meyer, L. Ackermann, "3d Metallaelectrocatalysis for Resource Economical Syntheses" Chem. Soc. Rev. 2020, 49, 4254-4272. Abstract>
380) Y. Zhang, J. Struwe, L. Ackermann, "Rhodium-Catalyzed Electrooxidative C–H Olefination of Benzamides" Angew. Chem. Int. Ed. 2020, 59, 15076-15080. Abstract>
379) X.-R. Chen, S.-Q. Zhang, T. H. Meyer, C.-H. Yang, Q.-H. Zhang, J.-R. Liu, H.-J. Xu, F.-H. Cao, L. Ackermann, X Hong, "Carboxylate Breaks Arene C–H Bond via a Hydrogen-Atom-Transfer Mechanism in Electrochemical Cobalt Catalysis" Chem. Sci. 2020, 11, 5790-5796. Abstract>
378) N. W. J. Ang, J. C. A. Oliveira, L. Ackermann, "Electro-Reductive Cobalt-Catalyzed Carboxylation: Cross-Electrophile Electro-coupling with Atmospheric CO2" Angew. Chem. Int. Ed. 2020, 59, 12842-12847. Abstract>
377) Y.-F. Liang, L. Yang, B. B. Jei, R. Kuniyil, L. Ackermann, "Regioselective B(3,4)–H Arylation of o-Carboranes by Weak Amide Coordination at Room Temperature" Chem. Sci. 2020, 11, 10764-10769. Abstract>
376) R. C. Samanta, J. Struwe, L. Ackermann, "Nickelaelectro-Catalyzed Mild C–H Alkylations at Room Temperature" Angew. Chem. Int. Ed. 2020, 59, 14154-14159. Abstract>
375) S.-K. Zhang, R. C. Samanta, A. Del Vecchio, L. Ackermann, "Evolution of High-Valent Nickelaelectro-Catalyzed C–H Activation: From Cross(-Electrophile)-Couplings to Electrooxidative C–H Transformations" Chem. Eur. J. 2020, 26, 10936-10947. Abstract>
374) U. Dhawa, C. Tian, T. Wdowik, J. C. A. Oliveira, J. Hao, L. Ackermann, "Enantioselective Palladaelectro‐Catalyzed C–H Activations by Transient Directing Groups: Expedient Access to Helicenes" Angew. Chem. Int. Ed. 2020, 59, 13451-13457. Abstract> (highlighted on Synfacts 2020, 6, 651) (Selected as hot paper)
373) J. Wu, N. Kaplaneris, S. Ni, F. Kaltenhäuser, L. Ackermann, "Late-Stage C(sp2)−H and C(sp3)−H Glycosylation for C-Aryl/Alkyl Glycopeptides: Mechanistic Insights and Fluorescence Labeling" Chem. Sci. 2020, 11, 6521-6526. Abstract>
372) C. Zhu, R. Kuniyil, B. B. Jei, L. Ackermann, "Domino C–H Activation/Directing Group Migration/Alkyne Annulation: Unique Selectivity by d6-Cobalt(III) Catalysts" ACS Catal. 2020, 10, 4444-4450. Abstract>
371) T. H. Meyer, J. C. A. Oliveira, D. Ghorai, L. Ackermann, "Insights into Cobalta(III/IV/II)-Electrocatalysis: Oxidation-Induced Reductive Elimination for Twofold C–H Activation" Angew. Chem. Int. Ed. 2020, 59, 10955-10960. Abstract>
370) E. N. da Silva Júnior, R. L. de Carvalho, R. G. Almeida, L. G. Rosa, F. Fantuzzi, T. Rogge, P. M. S. Costa, C. Pessoa, C. Jacob, L. Ackermann, "Ruthenium(II)‐Catalyzed Double Annulation of Quinones: Step‐Economical Access to Valuable Bioactive Compounds" Chem. Eur. J. 2020, 26, 10981-10986. Abstract>
369) L. Yang, R. Steinbock, A. Scheremetjew, R. Kuniyil, L. H. Finger, A. M. Messinis, L. Ackermann, "Aza-Ruthena(II)-Bicyclo-[3.2.0]-Heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-Catalyzed Alkyne Annulations" Angew. Chem. Int. Ed. 2020, 59,11130-11135. Abstract> (highlighted in ChemistryViews)
368) A. Kharma, C. Jacob, Í. A. O. Bozzi, G. A. M. Jardim, A. L. Braga, K. Salomão, C. C. Gatto, M. F. S. Silva, C. Pessoa, M. Stangier, L. Ackermann, E. N. da Silva Júnior, "Electrochemical selenation/cyclization of quinones: A rapid, green and efficient access to functionalized trypanocidal and antitumor compounds" Eur. J. Org. Chem. 2020, 4474-4486. Abstract>
367) W. Ma, N. Kaplaneris, X. Fang, L. Gu, R. Mei, L. Ackermann, "Chelation-Assisted Transition Metal-Catalysed C–H Chalcogenylations" Org. Chem. Front. 2020, 7, 1022-1060. Abstract>
366) I. Choi, V. Müller, G. Lole, R. Köhler, V. Karius, W. Viöl, C. Jooß, L. Ackermann, "Photo-Induced Heterogeneous C–H Arylation by Reusable Hybrid-Copper Catalyst" Chem. Eur. J. 2020, 26, 3509-3514. Abstract>
365) R. Mei, U. Dhawa, R. C. Samanta, W. Ma, J. Wencel-Delord, L. Ackermann, "Cobalt‐Catalyzed Oxidative C−H Activation: Strategies and Concepts" ChemSusChem 2020, 13, 3306-3356. Abstract>
364) T. H. Meyer, G. A. Chesnokov, L. Ackermann, "Cobaltaelectro-Catalyzed C–H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy" ChemSusChem 2020, 13, 668-671. Abstract>
363) L. Ackermann, "Metallaelectro-Catalyzed C–H Activation by Earth-Abundant 3d Metals and Beyond" Acc. Chem. Res. 2020, 53, 84-104. Abstract>
362) Y. Qiu, A. Scheremetjew, L. H. Finger, L. Ackermann, "Electrophotocatalytic Undirected C–H Trifluoromethylations of (Het)Arenes" Chem. Eur. J. 2020, 26, 3241-3246. Abstract>
361) R. Mei, X. Fang, L. He, J. Sun, L. Zou, W. Ma, L. Ackermann, "Cobaltaelectro-Catalyzed Oxidative Allene Annulation by Electro-Removable Hydrazides" Chem. Commun. 2020, 56, 1393-1396. Abstract>
360) W.-J. Kong,' Z. Shen,' L. H. Finger, L. Ackermann, "Electrochemical Access to Aza-Polycyclic Aromatic Hydrocarbons: Rhodaelectro-Catalyzed Domino Annulations" Angew. Chem. Int. Ed. 2020, 59, 5551-5556. ' These authors contributed equally. Abstract>
359) C. Tian,' T. H. Meyer,' M. Stangier, U. Dhawa, K. Rauch, L. H. Finger, L. Ackermann, "Cobaltaelectro-Catalyzed C–H Activation for Resource-Economical Molecular Syntheses" Nature Protocols 2020, 15, 1760–1774. ' These authors contributed equally. Abstract>
358) L. Massignan,' X. Tan,' T. H. Meyer, R. Kuniyil, A. M. Messinis, L. Ackermann, "C−H Oxygenation Reactions Enabled by Dual Catalysis with Electrogenerated Hypervalent Iodine Species and Ruthenium Complexes" Angew. Chem. Int. Ed. 2020, 59, 3184-3189. ' These authors contributed equally. Abstract>
357) U. Dhawa, I. Choi, L. Ackermann, "C–H Carboxylations with CO2", in CO2 Chemistry (Eds.: S. Das), Wiley-VCH, Weinheim, 2020. Abstract>
356) K. Korvorapun, R. Kuniyil, L. Ackermann, "Late-Stage Diversification by Selectivity Switch in meta-C–H Activation: Evidence for Singlet Stabilization" ACS Catal. 2020, 10, 435-440. Abstract>
355) Z. Xu, Z. Huang, Y. Li, R. Kuniyil, C. Zhang, L. Ackermann, Z. Ruan, "Catalyst-Free, Direct Electrochemical Synthesis of Annulated Medium-Sized Lactams through C‒C Bond Cleavage" Green Chem. 2020, 22, 1099-1104. Abstract>
354) S.-K. Zhang, J. Struwe, L. Hu, L. Ackermann, "Nickela-electrocatalyzed C–H Alkoxylation with Secondary Alcohols: Oxidation-Induced Reductive Elimination at Nickel(III)" Angew. Chem. Int. Ed. 2020, 59, 3178-3183. Abstract>
353) F. Ferlin, A. Marini, N. Ascani, L. Ackermann, D. Lanari, L. Vaccaro, "Heterogeneous Manganese-Catalyzed Oxidase C–H/C–O Cyclization to Access Pharmaceutically Active Compounds" ChemCatChem 2020, 12, 449-454. Abstract>
352) V. Müller, R. Weck, V. Derdau, L. Ackermann, "Ruthenium(II)-Catalyzed Hydrogen Isotope Exchange of Pharmaceutical Drugs by C–H Deuteration and C–H Tritiation" ChemCatChem 2020, 12, 100-104. Abstract>
351) C. Zhu, M. Stangier, J. C. A. Oliveira, L. Massignan, L. Ackermann, "Iron-Electro-Catalyzed C–H Arylations: Mechanistic Insights Into Oxidation-Induced Reductive Elimination through Spectroscopy, CV, and Computation for Ferraelectrocatalysis" Chem. Eur. J. 2019, 25, 16382-16389. Abstract>
350) E. Gońka,’ L. Yang,’ R. Steinbock, F. Pescaioli, R. Kuniyil, L. Ackermann, "π-Extended Polyaromatic Hydrocarbons by Sustainable Alkyne Annulations through Double C–H/N–H Activation" Chem. Eur. J. 2019, 25, 16246-16250. ' These authors contributed equally. Abstract>
349) W.-J. Kong, L. H. Finger, A. M. Messinis, R. Kuniyil, J. C. A. Oliveira, L. Ackermann, "Flow Rhodaelectro-Catalyzed Alkyne Annulations by Versatile C−H Activation: Mechanistic Support for Rhodium(III/IV)" J. Am. Chem. Soc. 2019, 141, 17198-17206. Abstract>
348) L. Capdevila, T. H. Meyer, S. Roldán-Gómez, J. M. Luis, L. Ackermann, X. Ribas, "Chemo-Divergent Nickel(0)-Catalyzed Arene C–F Activation with Alkynes: Unprecedented C-F/C-H Double-Insertion" ACS Catal. 2019, 9, 11074-11081. Abstract>
347) T. Rogge, L. Ackermann, "Arene-Free Ruthenium(II/IV)-Catalyzed Bifurcated Arylation for Oxidative C–H/C–H Functionalizations" Angew. Chem. Int. Ed. 2019, 58, 15640-15645. Abstract>
346) J. Jiang, H. Liu, L. Cao, C. Zhao, Y. Liu, L. Ackermann, Z. Ke, "Metallalkenyl, Metallacyclopropene, or Metallallylcarbenoid? Ru-Catalyzed Annulation between Benzoic Acid and Alkyne" ACS Catal. 2019, 9, 9387-9392. Abstract>
345) S. Chen, W. Chen, X. Chen, G. Chen, L. Ackermann, X. Tian, "Copper(I)-Catalyzed Oxyamination of β,γ-Unsaturated Hydrazones: Synthesis of Dihydropyrazoles" Org. Lett. 2019, 21, 7787-7790. Abstract>
344) L. Ackermann, J.-P. Sortais, "HomogeneousCatalysisis Up for the Challenge" ChemCatChem 2019, 11, 5158-5159. Abstract>
343) J. A. Ellman, L. Ackermann, B.-F. Shi, "The Breadth and Depth of C-H Functionalization" J. Org. Chem. 2019, 84, 12701-12704. Abstract>
342) M. Virelli,' W. Wang,' R. Kuniyil, J. Wu, G. Zanoni, A. Fernandez, J. Scott, M Vendrel, L. Ackermann, "BODIPY-Labeled Cyclobutanes by Secondary C(sp3)─H Arylations for Live-Cell Imaging" Chem. Eur. J. 2019, 25, 12712-12718. ' These authors contributed Abstract>
341) A. Çapcı, M. M. Lorion, H. Wang, N. Simon, M. Leidenberger, M. C. Borges Silva, D. R. M. Moreira, Z. Yongping, M. Yuqing, C. J. Yun, Y. M. Lee, O. Friedrich, B. Kappes, J. Wang, L. Ackermann, S. B. Tsogoeva, "Artemisinin‐(Iso)Quinoline Hybrids by C‐H Activation and Click Chemistry: Combating Multidrug‐Resistant Malaria" Angew. Chem. Int. Ed. 2019, 58, 13066-13079. Abstract> (highlighted in Nature)
340) T. E. Boddie, S. H. Carpenter, T. M. Baker, J. C. DeMuth, G. Cera, W. W. Brennessel, L. Ackermann, M. L. Neidig, "Identification and Reactivity of Cyclometalated Iron(II) Intermediates in Triazole-Directed Iron-Catalyzed C-H Activation" J. Am. Chem. Soc. 2019, 141, 12338-12345. Abstract>
339) C. Tian, U. Dhawa, A. Scheremetjew, L. Ackermann, "Cupraelectro-Catalyzed Alkyne Annulation: Evidence for Distinct C–H Alkynylation and Decarboxylative C–H/C–C Manifolds" ACS Catal. 2019, 9, 7690-7696. Abstract>
338) A. Schischko,' N. Kaplaneris,' T. Rogge, G. Sirvinskaite, J. Son, L. Ackermann, "Late-stage peptide C–H alkylation for bioorthogonal C–H activation featuring solid phase peptide synthesis" Nature Commun. 2019, 10, 3553. ' These authors contributed equally. Abstract>
337) R. Mei, W. Ma, Y. Zhang, X. Guo, L. Ackermann, "Cobaltaelectro-Catalyzed Oxidative C−H/N−H Activation with 1,3-diynes by Electro-Removable Hydrazides" Org. Lett. 2019, 21, 6534-6538. Abstract>
336) F. Ferlin, S. R. Yetra, Svenja Warratz, L. Vaccaro, L. Ackermann, "Reusable Pd@PEG Catalyst for Aerobic Dehydrogenative C–H/C–H Arylations of 1,2,3-Triazoles" Chem. Eur. J. 2019, 25, 11427-11431. Abstract>
335) W. Wang,' P. Subramanian,' O. Martinazzoli, J. Wu, L. Ackermann, "Glycopeptides by Linch-Pin C–H Activations for Peptide-Carbohydrate Conjugation by Manganese(I)-Catalysis" Chem. Eur. J. 2019, 25, 10585-10589. ' These authors contributed equally. Abstract>
334) J. Mo,' T. Müller,' J. C. A. Oliveira,' S. Demeshko, F. Meyer, L. Ackermann, "Iron‐Catalyzed C–H Activation with Propargyl Acetates: Mechanistic Insights on Iron(II) by Experiment, Kinetics, Mössbauer Spectroscopy and Computation" Angew. Chem. Int. Ed. 2019, 58, 12874-12878. ' These authors contributed equally. Abstract>
333) E. N. da Silva Júnior, G. A. M. Jardim, C. Jacob, U. Dhawa, L. Ackermann, S. L. de Castro, "Synthesis of quinones with highlighted biological applications: A critical update on the strategies towards bioactive compounds with emphasis on lapachones" Eur. J. Med. Chem. 2019, 179, 863-915. Abstract>
332) P. Gandeepan, J. Koeller, K. Korvorapun, J. Mohr, L. Ackermann, "Visible-Light for Ruthenium-Catalyzed meta-C‒H Alkylation at Room Temperature" Angew. Chem. Int. Ed. 2019, 58, 9820-9825. Abstract>
331) J. Loup, U. Dhawa, F. Pesciaioli, J. Wencel-Delord, L. Ackermann, "Enantioselective C-H Activation with Earth-Abundant 3d Transition Metals" Angew. Chem. Int. Ed. 2019, 58, 12803-12818. Abstract>
330) T. H. Meyer, L. H. Finger, P. Gandeepan, L. Ackermann, "Resource Economy by Metallaelectrocatalysis: Merging Electrochemistry and C–H Activation" Trends Chem. 2019, 1, 63-76. Abstract>
329) W.-J. Kong, L. H. Finger, J. C. A. Oliveira, L. Ackermann, "Rhodaelectrocatalysis for Annulative C–H Activation: Polycyclic Aromatic Hydrocarbons by Versatile Double Electrocatalysis" Angew. Chem. Int. Ed. 2019, 58, 6342-6346. Abstract>
328) Y. Qiu, J. Struwe, L. Ackermann, "Metallaelectro-Catalyzed C–H Activation by Weak Coordination" Synlett 2019, 30, 1164-1173. Abstract>
327) S. Chandra Sau, R. Mei, J. Struwe, L. Ackermann, "Cobaltaelectro-Catalyzed C–H Activation with Carbon Monoxide or Isocyanides" ChemSusChem 2019, 12, 3023-3027. Abstract>
326) S. Han, S. Liu, L. Liu, L. Ackermann, J. Li, "Cobalt-Catalyzed Diastereoselective Difluoroalkylation/Giese Addition Domino Reactions" Org. Lett. 2019, 21, 5387-5391. Abstract>
325) G. Parthasarathy, N. Kaplaneris, S. Santoro, L. Vaccaro, L. Ackermann, "Biomass-Derived Solvents for Sustainable Transition Metal-Catalyzed C-H Activation" ACS Sustain. Chem. Eng. 2019, 7, 8023-8040. Abstract>
324) J. Loup, T. Parchomyk, S. Lülf, S. Demeshko, F. Meyer, K. Koszinowski, L. Ackermann, "Mössbauer and mass spectrometry support for iron(II) catalysts in enantioselective C–H activation" Dalton Trans. 2019, 48, 5135-5139. Abstract>
323) H. Long, K. Xu, S. Chen, J. Lin, D. Wu, B. Wu, X. Tian, L. Ackermann, "Nickel-Catalyzed Intramolecular Direct Arylation of Imines towards Diverse Indoles" Org. Lett. 2019, 21, 3053-3056. Abstract>
322) S. Santoro, F.Ferlin, L. Ackermann, L. Vaccaro, "C–H Functionalization Reactions in Flow Conditions" Chem. Soc. Rev. 2019, 48, 2767-2782. Abstract>
321) S. R. Yetra, T. Rogge, S. Warratz, J. Struwe, W. Peng, P. Vana, L. Ackermann, "Micellar Catalysis for Ruthenium(II)-Catalyzed C−H Arylation: Weak-Coordination-Enabled C−H Activation in H2O" Angew. Chem. Int. Ed. 2019, 58, 7490-7494. Abstract>
320) P. Gandeepan, T. Müller, D. Zell, G. Cera, S. Warratz, L. Ackermann, "3d Transition Metals for C–H Activation" Chem. Rev. 2019, 119, 2192-2452. Abstract>
319) P. Chen, Y. Hao, X. Wang, D. Yuan, Y. Yao, L. Ackermann, "Directing Group-free C7-alkylations of N-alkylindols Mediated by Cationic Zirconium Complexes: Role of Brønsted Acid for Catalytic Manifold" Chem. Eur. J. 2019, 25, 7292-7297. Abstract>
318) P. Gandeepan, L. Ackermann, "Diastereoselective Formation of Alkenes through C(sp2)–H Bond Activation", in C–H-Activation for Asymmetric Synthesis(Eds.: F. Colobert, J. Wence-Delord), Wiley-VCH, Weinheim, 2019, 239-281. Abstract>
317) C. Tian, U. Dhawa, J. Struwe, L. Ackermann, "Cobaltaelectro-Catalyzed C–H Acyloxylation" Chin. J. Chem. 2019, 37, 552-556. Abstract>
316) C. Zhu, R. Kuniyil, L. Ackermann, "Manganese(I)-Catalyzed C–H Activation/Diels-Alder/retro-Diels-Alder Domino Alkyne Annulation by Transformable Pyridines" Angew. Chem. Int. Ed. 2019, 58, 5338-5342. Abstract>
315) Z. Ruan, Z. Huang, Z. Xu, G. Mo, X. Tian,X.-Y. Yu, L. Ackermann, "Catalyst-Free, Direct Electrochemical Tri- and Difluoroalkylation/Cyclization: Access to Functionalized Oxindoles and Quinolinones" Org. Lett. 2019, 21, 1237-1240. Abstract>
314) Y. Qiu,' A. Scheremetjew', L. Ackermann, "Electrooxidative C–C Alkenylation by Rhodium(III) Catalysis" J. Am. Chem. Soc. 2019, 141, 2731-2738. ' Both authors contributed equally. Abstract>
313) Z. Shen, H. Huang, C. Zhu, S. Warratz, L. Ackermann, "MnCl2-Catalyzed C–H Alkylation on Azine Heterocycles" Org. Lett. 2019, 21, 571-574. Abstract>
312) D Ghorai, J. Loup, G. Zanoni, L. Ackermann, "Air-Stable Secondary Phosphine Oxides (SPOs) for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C–O Activation" Synlett 2019, 30, 429-432. Abstract>
311) G. G. Dias, T. A. do Nascimento, A. K. A. de Almeida, A. C. S. Bombaça, R. F. S. Menna-Barreto, C. Jacob, S. Warratz, E. N. da Silva Júnior, L. Ackermann, "Ruthenium(II)-Catalyzed C–H Alkenylation of Quinones: Diversity-Oriented Strategy for Trypanocidal Compounds" Eur. J. Org. Chem. 2019, 2344-2353. Abstract>
310) N. Kaplaneris, T. Rogge, R. Yin, H. Wang, G. Sirvinskaite, L. Ackermann, "Late-Stage Diversification by Manganese-Catalyzed C–H Activation: Access to Acyclic, Hybrid and Stapled Peptides" Angew. Chem. Int. Ed. 2019, 58, 3476-3480. Abstract>
309) J. Loup,' V. Müller,' D. Ghorai, L. Ackermann, "Enantioselective Aluminum-Free Alkene Hydroarylations via C–H Activation by a Chiral Nickel/JoSPOphos Manifold" Angew. Chem. Int. Ed. 2019, 58, 1749-1753. ' Both authors contributed equally. Abstract>
308) Q. Bu,' E. Gonka,' K. Kucinski, L. Ackermann, "Cobalt-Catalyzed Hiyama-type C-H Activation with Arylsiloxanes: Versatile Access to Highly-Ortho-Decorated Biaryls" Chem. Eur. J. 2019, 25, 2213-2216. ' Both authors contributed equally. Abstract>
307) M. Tang, Y. Li, S. Han, L. Liu, L. Ackermann, J. J. Li, "Rhodium(III)-Catalyzed C-H Alkylation/Nucleophilic Addition Domino Reaction" Eur. J. Org. Chem. 2019, 660-664. Abstract>
306) J. Koeller, P. Gandeepan, L. Ackermann, "Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature" Synthesis 2019, 51, 1284-1292. Abstract>
305) M. M. Lorion, N. Kaplaneris, J. Son, R. Kuniyil, L. Ackermann, "Late-Stage Peptide Diversification by Cobalt-Catalyzed C–H Activation: Sequential Multicatalysis for Stapled Peptides" Angew. Chem. Int. Ed. 2019, 58, 1684-1688. Abstract>
304) A. Bechtoldt, L. Ackermann, "Ruthenium(II)biscarboxylate-Catalyzed Hydrogen-Isotope Exchange by Alkene C–H Activation" ChemCatChem 2019, 11, 435-438. Abstract>
303) P. Gandeepan, L. Ackermann, "Organometallic Chelation-Assisted C–H Functionalization", in Non-Noble Metal Catalysis: Molecular Approaches and Reactions (Eds.: R. J. Klein Gebbink, M.-E. Moret), Wiley-VCH, Weinheim, 2019, pp. 391-424. Abstract>
302) W. Ma, Z. Weng, X, Fang, L. Gu, Y. Song, L. Ackermann, "Ruthenium-Catalyzed C–H Selenylations of Benzamides" Eur. J. Org. Chem. 2019, 41-45. Abstract>
301) F. Yang, H. Zhang, X. Liu, B. Wang, L. Ackermann, "Transition Metal-Catalyzed Regio-Selective Aromatic C–H Bond Oxidation for C–O Bond Formation" Chin. J. Org. Chem. 2019, 39, 59-73. Abstract>
300) H. Wang,' I. Choi,' T. Rogge, N. Kaplaneris, L. Ackermann, "Versatile and Robust C–C Activation by Chelation-Assisted Manganese-Catalysis" Nature Catal. 2018, 1, 993-1001. ' Both authors contributed equally. Abstract>
299) D. Ghorai, L. H. Finger, G. Zanoni, L. Ackermann, "Bimetallic Nickel Complexes for Aniline C–H Alkylations" ACS Catal. 2018, 8, 11657-11662. Abstract>
298) S.-K. Zhang, R. C. Samanta, N. Sauermann, L. Ackermann, "Nickel-Catalyzed Electrooxidative C–H Amination: Support for Nickel(IV)" Chem. Eur. J. 2018, 24, 19166-19170. Abstract>
297) F. Pesciaioli, U. Dhawa, J. C. A. Oliveira, R. Yin, M. John, L. Ackermann, "Enantioselective Cobalt(III)-Catalyzed C–H Activation Enabled by Chiral Carboxylic Acid Cooperation" Angew. Chem. Int. Ed. 2018, 57, 15425-15429. ' Both authors contributed equally. Abstract>
296) R. Mei, J. Koeller, L. Ackermann, "Electrochemical Ruthenium-Catalyzed Alkyne Annulations by C−H/Het−H Activation of Aryl Carbamates or Phenols in Protic Media" Chem. Commun. 2018, 54, 12879-12882. Abstract>
295) G. G. Dias, T. Rogge, R. Kuniyil, C. Jacob, R. F. S. Menna-Barreto, E. N. da Silva Júnior, L. Ackermann, "Ruthenium-catalyzed C–H oxygenation of quinones by weak O-coordination for potent trypanocidal agents" Chem. Commun. 2018, 54, 12840-12843. Abstract>
294) Y. Qiu,' M. Stangier,' T. H. Meyer, J. C. A. Oliveira, L. Ackermann, "Iridium-Catalyzed Electrooxidative C–H Activation by Chemo-Selective Redox-Catalyst Cooperation" Angew. Chem. Int. Ed. 2018, 57, 14179-14183. ' Both authors contributed equally Abstract>
293) Y.-F. Liang,' L. Yang,' T. Rogge,' L. Ackermann, "Ruthenium(IV) Intermediates in C−H Activation/Annulation by Weak O-Coordination" Chem. Eur. J. 2018, 24, 16548-16552. ' Both authors contributed equally Abstract>
292) T. H. Meyer, J. C. A. Oliveira, S. Chandra Sau, N. W. J. Ang, L. Ackermann, "Electrooxidative Allene Annulations by Mild Cobalt-Catalyzed C–H Activation" ACS Catal. 2018, 8, 9140-9147. Abstract>
291) M. Virelli, E. Moroni, G. Colombo, L. Fiengo, A. Porta, L. Ackermann, G. Zanoni, "Expedient Access to 2-Benzazepines by Palladium-Catalyzed C−H activation: Identification of a Unique HSP90 Inhibitor Scaffold" Chem. Eur. J. 2018, 24, 16516-16520. Abstract>
290) W. Wang,' M. M. Lorion,' O. Martinazzoli, L. Ackermann, "BODIPY Peptide Labeling by Late-Stage C(sp3)-H Activation" Angew. Chem. Int. Ed. 2018, 57, 10554-10558. ' Both authors contributed equally Abstract>
289) W. Wang,' M. M. Lorion,' J. Shah, A. R. Kapdi, L. Ackermann, "Late-Stage Peptide Diversification by Position- Selective C-H Activation" Angew. Chem. Int. Ed. 2018, 57, 14700-14717. ' Both authors contributed equally Abstract>
288) N. Sauermann, T. H. Meyer, Y. Qiu, L. Ackermann, "Electrocatalytic C–H Activation" ACS Catal. 2018, 8, 7086-7103. Abstract>
287) N. Sauermann, T. H. Meyer, L. Ackermann, "Electrochemical Cobalt-Catalyzed C–H Activation" Chem. Eur. J. 2018, 24, 16209-16217. Abstract>
286) Y.-F. Liang, R. Steinbock, L. Yang, L. Ackermann, "Continuous Visible Light-Photo-Flow Approach for Manganese-Catalyzed (Het)Arene C−H Arylation" Angew. Chem. Int. Ed. 2018, 57, 10625-10629. Abstract>
285) Y. Qiu,' J. Struwe,' T. H. Meyer, J. C. A. Oliveira, L. Ackermann, "Catalyst- and Reagent-free Electrochemical Azole C−H Amination" Chem. Eur. J. 2018, 24, 12784-12789. 'Both authors contributed equally Abstract>
284) S. R. Yetra,' Z. Shen,' H. Wang, L. Ackermann, "Thiocarbonyl-Enabled Ferrocene C–H Nitrogenation by Cobalt(III) Catalysis: Thermal and Mechanochemical" Beilstein J. Org. Chem. 2018, 14, 1546-1553. 'Both authors contributed equally Abstract>
283) R. Mei, N. Sauermann, J. C. A. Oliveira, L. Ackermann, "Electro-Removable Traceless Hydrazides for Cobalt-Catalyzed Electro-Oxidative C–H/N–H Activation with Internal Alkynes" J. Am. Chem. Soc. 2018, 140, 7913-7921. Abstract>
282) J. Mo,' T. Müller,' J. C. A. Oliveira, L. Ackermann, "1,4-Iron Migration for Expedient Allene Annulations through Iron-Catalyzed C–H/N–H/C–O/C–H Functionalizations" Angew. Chem. Int. Ed. 2018, 57, 7719-7723. 'Both authors contributed equally Abstract>
281) F. Ferlin, L. Luciani, S. Santoro, A. Marrocchi, D. Lanari, A. Bechtoldt, L. Ackermann, L. Vaccaro, "A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as biomass-derived medium" Green Chem. 2018, 20, 2888-2893. Abstract>
280) E. Detmar, V. Müller, D. Zell, L. Ackermann, M. Breugst, "Cobalt-Catalyzed C–H Cyanations: Insights into the Reaction Mechanism and the Role of London Dispersion" Beilstein J. Org. Chem. 2018, 14, 1537-1545. Abstract>
279) Y. Fang, T. Rogge, L. Ackermann, S.-Y. Wang, S.-J. Ji, "Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides" Nature Commun. 2018, 9, 2240. Abstract>
278) E. N. da Silva Júnior, G. A. M. Jardim, R. S. Gomes, Y.-F. Liang, L. Ackermann, "Weakly-coordinating N-oxide and carbonyl groups for metal-catalyzed C–H activation: The case of A-ring functionalization" Chem. Commun. 2018, 54, 7398-7411. Abstract>
277) Y. Qiu,' W.-J. Kong,' J. Struwe, N. Sauermann, T. Rogge, A Scheremetjew, L. Ackermann, "Electrooxidative Rhodium-Catalyzed C–H/C–H Activation: Electricity as Oxidant for Cross-Dehydrogenative Alkenylation" Angew. Chem. Int. Ed. 2018, 57, 5828-5832. 'Both authors contributed equally Abstract> (highlighted in ChemistryViews)
276) J. Kalepu, P. Gandeepan, L. Ackermann, L. Pilarski, "C4-H Indole Functionalisation: Precedent and Prospects" Chem. Sci. 2018, 9, 4203-4216. Abstract>
275) S. Santoro, A. Marrocchi, D. Lanari, L. Ackermann, L. Vaccaro, "Towards Sustainable C–H Functionalization Reactions: The Emerging Role of Bio-Based Reaction Media" Chem. Eur. J. 2018, 24, 13383-13390. Abstract>
274) U. Dhawa, D. Zell, R. Yin, S. Okumura, M. Murakami, L. Ackermann, "C–H/C–F Functionalization by E-Selective Ruthenium(II)-Catalysis" J. Catal. 2018, 364, 14-18. Abstract>
273) C. Zhu, J. C. A. Oliveira, Z. Shen, H. Huang, L. Ackermann, "Manganese(II/III/I)-Catalyzed C–H Arylations in Continuous Flow" ACS Catal. 2018, 8, 4402-4407. Abstract>
272) Y. Qiu, C. Tian, L. Massignan, T. Rogge, L. Ackermann, "Electrooxidative Ruthenium-Catalyzed C–H/O–H Annulation by Weak O-Coordination" Angew. Chem. Int. Ed. 2018, 57, 5818-5822. Abstract>
271) N. Sauermann, R. Mei, L. Ackermann, "Electrochemical C–H Amination by Cobalt Catalysis in a Renewable Solvent" Angew. Chem. Int. Ed. 2018, 57, 5090-5094. Abstract>
270) Y.-F. Liang, R. Steinbock, A. Münch, D. Stalke, L. Ackermann, "Manganese-Catalyzed Carbonylative Annulations for Redox-Neutral Late-Stage Diversification" Angew. Chem. Int. Ed. 2018, 57, 5384-5388. Abstract>
269) Y.-F. Liang, L. Massignan, L. Ackermann, "Sustainable Manganese-Catalyzed C–H Activation/Hydroarylation of Imines" ChemCatChem 2018, 10, 2768-2772. Abstract>
268) F. Fumagalli, S. Warratz, S.-K. Zhang, T. Rogge, C. Zhu, A. C. Stückl, L. Ackermann, "Arene-Ligand-free Ruthenium(II/III) Manifold for meta-C–H Alkylation: Remote Purine Diversification" Chem. Eur. J. 2018, 24, 3984-3988. Abstract>
267) C. Tian, L. Massignan, T. H. Meyer, L. Ackermann, "Electrochemical C–H/N–H Activation by Water-Tolerant Cobalt-Catalysis at Room Temperature" Angew. Chem. Int. Ed. 2018, 57, 2383-2387. Abstract>
266) A. Bechtoldt, M. E. Baumert, L. Vaccaro, L. Ackermann, "Ruthenium(II) oxidase catalysis for C–H alkenylations in biomass-derived γ-valerolactone" Green Chem. 2018, 20, 398-402. Abstract>
265) Q. Bu,' T. Rogge,' V. Kotek, L. Ackermann, "Distal Weak Coordination of Acetamides in Ruthenium(II)-Catalyzed C–H Activation Processes" Angew. Chem. Int. Ed. 2018, 57, 765-768. 'Both authors contributed equally. Abstract>
264) K. Korvorapun, N. Kaplaneris, T. Rogge, S. Warratz, A. C. St ckl, L. Ackermann, "Sequential meta-/ortho-C–H Functionalizations by One-Pot Ruthenium(II/III) Catalysis" ACS Catal. 2018, 8, 886-892. Abstract>
263) W. Ma, Z. Weng, T. Rogge, L. Gu, J. Lin, A. Peng, X. Luo, X. Gou, L. Ackermann, "Ruthenium-Catalyzed C–H Chalcogenation of Anilines" Adv. Synth. Catal. 2018, 360, 704-710. Abstract>
262) P. Gandeepan, L. Ackermann, "Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis" Chem 2018, 4, 199-222. Abstract>
261) M. Bauer,' W. Wang,' M. M. Lorion, C. Dong, L. Ackermann, "Internal Peptide Late-Stage Diversification: Peptide Isosteric Triazoles for Primary and Secondary C(sp3)–H Activation" Angew. Chem. Int. Ed. 2018, 57, 203-207. 'Both authors contributed equally. Abstract>
260) Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds (Eds.: L. G. Habgood, T. B. Gunnoe, L. Ackermann), Wiley-VCH, Weinheim, 2018. ISBN: 978-3-527-34013-2 Content>
259) N. Sauermann,' T. H. Meyer,' C. Tian, L. Ackermann, "Electrochemical Cobalt-Catalyzed C-H Oxygenation at Room Temperature" J. Am. Chem. Soc. 2017, 139, 18452-18455. 'Both authors contributed equally. Abstract>
258) S. Nakanowatari,' T. M ller,' J. C. A. Oliveira, L. Ackermann, "Bifurcated Nickel-Catalyzed Functionalizations: Heteroarene C-H Activation with Allenes" Angew. Chem. Int. Ed. 2017, 56, 15891-15895. 'Both authors contributed equally. Abstract>
257) M. M. Lorion, K. Maindan, A. R. Kapdi, L. Ackermann, "Heteromultimetallic Catalysis for Sustainable Organic Syntheses" Chem. Soc. Rev. 2017, 46, 7399-7420. Abstract>
256) H. Wang,' F. Pesciaioli,' J. C. A. Oliveira, S. Warratz, L. Ackermann, "Synergistic Manganese(I) C-H Activation Catalysis in Continuous Flow: Chemoselective Hydroarylation" Angew. Chem. Int. Ed. 2017, 56, 15063-15067. 'Both authors contributed equally. Abstract>
255) J. Loup, D. Zell, J. C. A. Oliveira, H. Keil, D. Stalke, L. Ackermann, "Asymmetric Iron-Catalyzed C-H Alkylation Enabled by Remote Ligand meta-Substitution" Angew. Chem. Int. Ed. 2017, 56, 14197-14201. Abstract>
254) N. Y. P. Kumar,' T. Rogge,' S. R. Yetra,' A. Bechtoldt, E. Clot, L. Ackermann, "Mild Decarboxylative C-H Alkylation: Computational Insights for Solvent-Robust Ruthenium(II) Domino Manifold" Chem. Eur. J. 2017, 23, 17449-17453. 'These authors contributed equally. Abstract>
253) H. Huang, S. Nakanowatari, L. Ackermann, "Selectivity Control in Ruthenium(II)-Catalyzed C-H/N-O Activation with Alkynylbromides" Org. Lett. 2017, 19, 4620-4623. Abstract>
252) Z. Ruan, D. Ghorai, G. Zanoni, L. Ackermann, "Nickel-Catalyzed C-H Activation of Purine Bases with Alkyl Halides" Chem. Commun. 2017, 53, 9113-9116. Abstract>
251) R. Mei,' S.-K. Zhang,' L. Ackermann, "Concise Synthesis of Lamellarin Alkaloids by C-H/N-H Activation: Evaluation of Metal Catalysts in Oxidative Alkyne Annulation" Synlett 2017, 28, 1715-1718. 'Both authors contributed equally. Abstract>
250) W. Liu, G. Cera, J. C. A. Oliveira, Z. Shen, L. Ackermann, "MnCl2-Catalyzed C-H Alkylations with Alkyl Halides" Chem. Eur. J. 2017, 23, 11524-11528. Abstract>
249) D. Zell, M. Bursch, V. M ller, S. Grimme, L. Ackermann, "Switch of C-H Activation Mechanism for Full Selectivity Control in Cobalt(III)-Catalyzed C-H Alkylations" Angew. Chem. Int. Ed. 2017, 56, 10378-10382. Abstract>
248) D. Ghorai, V. M ller, H. Keil, D. Stalke, G. Zanoni, B. A. Tkachenko, Peter R. Schreiner, L. Ackermann, "Secondary Phosphine Oxide Preligand for Palladium-Catalyzed C-H (Hetero)Arylations: Efficient Access to Pybox Ligands" Adv. Synth. Catal. 2017, 359, 3137-3141. Abstract>
247) Z. Shen,' G. Cera,' T. Haven , L. Ackermann, "Tri-Substituted Triazole-Enabled C-H Activation of Benzyl and Aryl Amines by Iron-Catalysis" Org. Lett. 2017, 19, 3795-3798. 'Both authors contributed equally. Abstract>
246) D. Zell, V. M ller, U. Dhawa, M. Bursch, R. R. Presa, S. Grimme, L. Ackermann, "Mild Cobalt(III)-Catalyzed Allylative C-F/C-H Functionalizations at Room Temperature" Chem. Eur. J. 2017, 23, 12145-12148. Abstract> (highlighted in ChemistryViews)
245) Y.-F. Liang, V. M ller, W. Liu, A. M nch, D. Stalke, L. Ackermann, "Methylenecyclopropane Annulation by Manganese(I)-Catalyzed Stereoselective C-H/C-C Activation" Angew. Chem. Int. Ed. 2017, 56, 9415-9419. Abstract>
244) G. Cera,' T. Haven,' L. Ackermann, "Iron-Catalyzed C-H/N-H Activation by Triazole Guidance: Versatile Alkyne Annulation" Chem. Commun. 2017, 53, 6460-6463. 'Both authors contributed equally. Abstract>
243) Z. Zhang, S. Han, M. Tang, L. Ackermann, J. Li, "C-H Alkylations of (Hetero)Arenes by Maleimides and Maleate Esters through Cobalt(III) Catalysis" Org. Lett. 2017, 19, 3315-3318. Abstract>
242) R. Mei, S.-K. Zhang, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Alkynylation of Weakly-Coordinating Benzoic Acids" Org. Lett. 2017, 19, 3171-3174. Abstract>
241) P. Gandeepan, J. Mo, L. Ackermann, "Photo-induced Copper-Catalyzed C-H Chalcogenation of Azoles at Room Temperature" Chem. Commun. 2017, 53, 5906-5909. Abstract>
240) D. Zell, U. Dhawa, V. M ller, M. Bursch, S. Grimme, L. Ackermann, "C-F/C-H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations" ACS Catal. 2017, 7, 4209-4213. Abstract>
239) H. Wang,' M. M. Lorion,' L. Ackermann, "Air-Stable Manganese(I)-Catalyzed C-H Activation for Decarboxylative C-H/C-O Cleavages on H2O" Angew. Chem. Int. Ed. 2017, 56, 6339-6342. 'Both authors contributed equally. Abstract>
238) F. Ferlin, S. Santoro, L. Ackermann, L. Vaccaro, "Heterogeneous C-H Alkenylations in Continuous-Flow: Oxidative Palladium-Catalysis in a Biomass-Derived Reaction Medium" Green Chem. 2017, 19, 2510-2514. Abstract>
237) N. Sauermann, J. Loup, D. Kootz, A. Berkessel, L. Ackermann, "Triazolylidene Ligands Allow Cobalt-Catalyzed C-H/C-O Alkenylations at Ambient Temperature" Synthesis 2017, 49, 3476-3484. Abstract>
236) H. Wang, M. M. Lorion, L. Ackermann, "Domino C-H/N-H Allylations of Imidates by Cobalt Catalysis" ACS Catal. 2017, 7, 3420-3433. Abstract>
235) M. Moselage,' J. Li,' F. Kramm, L. Ackermann, "Ruthenium(II)-Catalyzed C-C Arylations and Alkylations: Decarbamoylative C-C Functionalizations" Angew. Chem. Int. Ed. 2017, 56, 5341-5344. 'Both authors contributed equally. Abstract>
234) J. Li,' K. Korvorapun,' S. De Sarkar,' T. Rogge, D. J. Burns, S. Warratz, L. Ackermann, "Ruthenium(II)-catalysed remote C-H alkylations as a versatile platform to meta-decorated arenes" Nature Commun. 2017, 8, 15430. 'Both authors contributed equally. Abstract>
233) T. H. Meyer,' W. Liu,' M. Feldt, A. Wuttke, R. A. Mata, L. Ackermann, "Manganese(I)-Catalyzed Dispersion-Enabled C-H/C-C Activation" Chem. Eur. J. 2017, 23, 5443-5447. 'Both authors contributed equally. Abstract>
232) W. Ma, P. Gandeepan, J. Li, L. Ackermann, "Recent advances in positional-selective alkenylations: Removable guidance for twofold C-H activation" Org. Chem. Front. 2017, 4, 1435-1467. Abstract>
231) S. Nakanowatari, R. Mei, M. Feldt, L. Ackermann, "Cobalt(III)-Catalyzed Hydroarylation of Allenes via C-H Activation" ACS Catal. 2017, 7, 2511-2515. Abstract>
230) G. Cera, T. Haven, L. Ackermann, "Iron-Catalyzed C-H Alkynylation through Triazole Assistance: Expedient Access to Bioactive Heterocycles" Chem. Eur. J. 2017, 23, 3577-3582. Abstract>
229) GK. Raghuvanshi, D. Zell, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Oxygenations of Reusable Sulfoximine Benzamides" Org. Lett. 2017, 19, 1278-1281. Abstract>
228) S. Santoro, F. Ferlin, L. Luciania, L. Ackermann, L. Vaccaro, "Biomass-derived solvents as effective media for cross-coupling reactions and C-H functionalization processes" Green Chem. 2017, 19, 1601-1612. Abstract>
227) Z. Ruan,' N. Sauermann,' E. Manoni, L. Ackermann, "Manganese-Catalyzed C-H Alkynylation: Expedient Peptide Synthesis and Modification" Angew. Chem. Int. Ed. 2017, 56, 3172-3176. 'Both authors contributed equally. Abstract>
226) Z. Ruan,' S.-K. Zhang,' C. Zhu, P. N. Ruth, D. Stalke, L. Ackermann, "Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation" Angew. Chem. Int. Ed. 2017, 56, 2045-2049. 'Both authors contributed equally. Abstract>
225) P. Gandeepan, J. Koeller, L. Ackermann, "Expedient C-H Chalcogenation of Indolines and Indoles by Positional Selective Copper-Catalysis" ACS Catal. 2017, 7, 1030-1034. Abstract>
224) A. Schischko, H. Ren, N. Kaplaneris, L. Ackermann, "Bioorthogonal Diversification of Peptides through Selective Ruthenium(II)-Catalyzed C-H Activation" Angew. Chem. Int. Ed. 2017, 56, 1576-1580. Abstract> (highlighted in ChemistryViews)
223) S. Warratz, D. J. Burns, C. Zhu, K. Korvorapun, T. Rogge, J. Scholz, C. Jooss, D. Gelman, L. Ackermann, "meta-C-H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis" Angew. Chem. Int. Ed. 2017, 56, 1557-1560. Abstract>
222) S. Zhang, M. Tang, S. Han, L. Ackermann, J. Li, "Carboxylate Enhanced Rhodium(III)-Catalyzed Aryl C-H Alkylation with Conjugated Alkenes under Mild Conditions" J. Org. Chem. 2017, 82, 664-672. Abstract>
221) W. Ma, H. Dong, D. Wang, L. Ackermann, "Late-Stage Diversification of Non-Steroidal Anti-Inflammatory Drugs by Transition Metal-Catalyzed C-H Alkenylations, Thiolations and Selenylation" Adv. Synth. Catal. 2017, 359, 966-973. Abstract>
220) D. Tonin,' D. Zell,' V. M ller, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Methylation with Trifluoroborates" Synthesis 2017, 49, 127-134. 'Both authors contributed equally. Abstract>
219) S. De Sarkar,' N. Y. P. Kumar,' L. Ackermann, "Ruthenium(II)Biscarboxylate-Catalyzed Borylations of C(sp2)-H and C(sp3)-H Bonds" Chem. Eur. J. 2017, 23, 84-87. 'Both authors contributed equally. Abstract>
218) D. J. Burns, S. I. Kozhushkov, L. Ackermann, "Ruthenium Catalysts for the Alkylation of Functionalized Arenes and Heteroaromatic Substrates via Hydroarylation", in Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds (Eds.: L. G. Habgood, T. B. Gunnoe, L. Ackermann), Wiley-VCH, Weinheim, 2017. Content>
217) M. M. Lorion, L. Ackermann, e-EROS 2017, DOI: 10.1002/047084289X.rn02097. Abstract>
216) R. Mei,' C. Zhu,' Lutz Ackermann L. Ackermann, "Ruthenium(II)-Catalyzed C-H Functionalizations on Benzoic Acids with Aryl, Alkenyl and Alkynyl Halides by Weak-O-Coordination" Chem. Commun. 2016, 52, 13171-13174. 'Both authors contributed equally. Abstract>
215) W. Liu,' S. C. Richter,' R. Mei,' Milica Feldt, Lutz Ackermann L. Ackermann, "Synergistic Heterobimetallic Manifold for Expedient Manganese(I)-Catalyzed C-H Cyanation" Chem. Eur. J. 2016, 22, 17958-17961. 'Both authors contributed equally. Abstract>
214) Y.-F. Liang, L. Massignan, W. Liu, L. Ackermann, "Catalyst-Guided C=Het Hydroarylations via Manganese-Catalyzed Additive-Free C-H Activation" Chem. Eur. J. 2016, 22, 14856-14859. Abstract>
213) D. Santrač,' S. Cella,' W. Wang, L. Ackermann, "Palladium-Catalyzed C-H Arylation of Amides by Triazole Assistance" Eur. J. Org. Chem. 2016, 5429-5436. 'Both authors contributed equally. Abstract>
212) T. M ller, L. Ackermann, "Nickel-Catalyzed C-H Chalcogenation of Anilines" Chem. Eur. J. 2016, 22, 14151-14154. Abstract>
211) H. Wang,' M. M. Lorion,' L. Ackermann, "Overcoming the Limitations of C-H Activation with Strongly Coordinating N-Heterocycles by Cobalt Catalysis" Angew. Chem. Int. Ed. 2016, 55, 10386-10390. 'Both authors contributed equally. Abstract>
210) G. Cera, L. Ackermann, "Iron-Catalyzed C-H Functionalization Processes" Top. Curr. Chem. 2016, 374, 191-224. Abstract>
209) X. Tian, F. Yang, D. Rasina, M. Bauer, S. Warratz, F. Ferlin, L. Vaccaro, L. Ackermann, "C-H Arylations of 1,2,3-Triazoles by Reusable Heterogeneous Palladium Catalysts in Biomass-Derived γ-Valerolactone" Chem. Commun. 2016, 52, 9777-9780. Abstract>
208) Z. Ruan, S. Lackner, L. Ackermann, "Nickel-Catalyzed C-H Alkynylation of Anilines: Expedient Access to Functionalized Indoles and Purine Nucleobases" ACS Catal. 2016, 6, 4690-4693. Abstract>
207) J. Hubrich, L. Ackermann, "Amino Acid Ligands for Ruthenium(II)-Catalyzed C-H Arylation of Aryltetrazoles with Chlorides: Expedient Access to Antihypertension Drugs" Eur. J. Org. Chem. 2016, 3700-3704. Abstract>
206) W. Liu, L. Ackermann, "Manganese-Catalyzed C-H Activation" ACS Catal. 2016, 6, 3743-3752. Abstract>
205) D. Rasina, A. Kahler-Quesada, S. Ziarelli, S. Warratz, H. Cao, S. Santoro, L. Ackermann, L. Vaccaro, "Heterogeneous Palladium-Catalysed Catellani Reaction in Biomass-Derived γ-Valerolactone" Green Chem. 2016, 18, 5025-5030. Abstract>
204) T. Himmler, L. Rodefeld, J. Hubrich, L. Ackermann, "Method for producing biphenylamines from azobenzenes by ruthenium catalysis" WO 2016071249 A1 20160512, 2016.
203) J. Li, M. Tang, L. Zang, X. Zhang, Z. Zhang, L. Ackermann, "Amidines for Versatile Cobalt(III)-Catalyzed Synthesis of Isoquinolines through C-H Functionalization with Diazo Compounds" Org. Lett.2016, 18, 2742-2745. Abstract>
202) D. Zell,' Q. Bu,' M. Feldt, L. Ackermann, "Mild C-H/C-C Activation by (Z)-Selective Cobalt-Catalysis" Angew. Chem. Int. Ed. 2016, 55, 7408-7412. 'Both authors contributed equally. Abstract>
201) T. Himmler, L. Rodefeld, J. Hubrich, L. Ackermann, "Method for production of biphenylamines from azobenzenes using ruthenium catalysis" EP 3015452 A1 20160504, 2016.
200) R. Mei, L. Ackermann, "Cobalt-Catalyzed C-H Functionalizations by Imidate Assistance with Aryl and Alkyl Chlorides" Adv. Synth. Catal. 2016, 358, 2443-2448. Selected as VIP paper. Abstract>
199) G. Cera, L. Ackermann, "Weak O-Assistance Outcompeting Strong N,N-bidentate Directing Groups in Copper-Catalyzed C-H Chalcogenation" Chem. Eur. J. 2016, 22, 8475-8478. Abstract>
198) K. Raghuvanshi, D. Zell, K. Rauch, L. Ackermann, "Ketone-Assisted Ruthenium(II)-Catalyzed C-H Imidation: Access to Primary Aminoketones by Weak Coordination" ACS Catal. 2016, 6, 3172-3175. Abstract>
197) W. Liu, S. C. Richter, Y. Zhang, L. Ackermann, "Manganese(I)-Catalyzed Substitutive C-H Allylation" Angew. Chem. Int. Ed. 2016, 55, 7747-7750. Abstract>
196) S. Fenner, L. Ackermann, "C-H Carboxylation of heteroarenes with ambient CO2" Green Chem. 2016, 18, 3804-3807. Abstract>
195) S. Santoro, S. I. Kozhushkov, L. Ackermann, L. Vaccaro, "Heterogeneous Catalytic Approaches in C-H Activation Reactions" Green Chem. 2016, 18, 3471-3493. Abstract>
194) R. Mei, H. Wang, S. Warratz, S. A. Macgregor, L. Ackermann, "Cobalt-Catalyzed Oxidase C-H/N-H Alkyne Annulation: Mechanistic Insights and Access to anti-Cancer Agents" Chem. Eur. J. 2016, 22, 6759-6763. Abstract>
193) H. Wang, M. Moselage, M. J. Gonz lez, L. Ackermann, "Selective Synthesis of Indoles by Cobalt(III)-Catalyzed C-H/N-O Functionalization with Nitrones" ACS Catal. 2016, 6, 2705-2709. Abstract>
192) N. Y. P. Kumar,' A. Bechtoldt,' K. Raghuvanshi, L. Ackermann, "Ruthenium(II)-Catalyzed Decarboxylative C-H-Activation: Versatile Routes to meta-Alkenylated Arenes" Angew. Chem. Int. Ed. 2016, 55, 6929-6932. 'Both authors contributed equally. Abstract> (highlighted in Nature Chem.)
191) F. Yang, J. Koeller, L. Ackermann, "Photo-Induced Copper-Catalyzed C-H Arylation at Room Temperature" Angew. Chem. Int. Ed. 2016, 55, 4759-4762. Abstract>(Selected as hot paper)
190) Z. Ruan,' S. Lackner,' L. Ackermann, "A General Strategy for Nickel-Catalyzed C-H Alkylation of Anilines" Angew. Chem. Int. Ed. 2016, 55, 3153-3157. 'Both authors contributed equally. Abstract> (Selected as hot paper)
189) R. Mei,' J. Loup,' L. Ackermann, "Oxazolinyl-Assisted C-H Amidation by Cobalt(III) Catalysis" ACS Catal. 2016, 6, 793-797. 'Both authors contributed equally. Abstract>
188) G. Cera, T. Haven, L. Ackermann, "Expedient Iron-Catalyzed C-H Allylation/Alkylation by Triazole Assistance with Ample Scope" Angew. Chem. Int. Ed. 2016, 55, 1484-1488. Abstract>
187) D. Zell,' S. Warratz,' D. Gelman, S. J. Garden, L. Ackermann, "Single-Component Phosphinous Acid Ruthenium(II) Catalysts for Versatile C-H Activations by Metal-Ligand Cooperation" Chem. Eur. J. 2016, 22, 1248-1252. 'Both authors contributed equally. Abstract>
186) M. Moselage, J. Li, L. Ackermann, "Cobalt-Catalyzed C-H Activation" ACS Catal. 2016, 6, 498-525. Abstract>
185) C. Borie, L. Ackermann, M. Nechab, "Enantioselective syntheses of indanes: from organocatalysis to C-H functionalization" Chem. Soc. Rev. 2016, 45, 1368-1386. Abstract>
184) A. Bechtoldt, C. Tirler, K. Raghuvanshi, S. Warratz, C. Kornhaa , L. Ackermann, "Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the Sole Oxidant" Angew. Chem. Int. Ed. 2016, 55, 264-267. Abstract>
183) J. Li, S. De Sarkar, L. Ackermann, "meta- and para-Selective C-H Functionalization by C-H Activation" Top. Organomet. Chem. 2016, 55, 217-257. Abstract>
182) N. Sauermann, M. J. Gonz lez, L. Ackermann, "Cobalt(III)-Catalyzed C-H Alkynylation with Bromoalkynes under Mild Conditions" Org. Lett. 2015, 17, 5316-5319. Abstract>
181) J. Li, S. Warratz, D. Zell, S. De Sarkar, E. E. Ishikawa, L. Ackermann, "N-Acyl Amino Acid Ligands for Ruthenium(II)-catalyzed meta-C-H tert-Alkylation with Removable Auxiliaries" J. Am. Chem. Soc. 2015, 137, 13894-13901. Abstract>(highlighted in ACS Cent. Sci.)
180) T. Himmler, L. Rodefeld, J. Hubrich, L. Ackermann, "Method for producing biphenylamines from anilides by ruthenium catalysis" WO 2015162144 A1 20151029 2015.
179) W. Liu, J. Bang, Y. Zhang, L. Ackermann, "Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes" Angew. Chem. Int. Ed. 2015, 54, 14137-14140. Abstract>(highlighted in Synfacts 2015, 1253)
178) H. Wang, J. Koeller, W. Liu, L. Ackermann, "Cobalt(III)-Catalyzed C-H/N-O Functionalizations: Isohypsic Access to Isoquinolines" Chem. Eur. J. 2015, 21, 15525-15528. Abstract>
177) T. Niklas, C. Steinmetzger, W. Liu, D. Zell, D. Stalke, L. Ackermann, M. John, "Determination of the Relative Configuration of β-Amino Acid Esters Based on Residual Dipolar Couplings" Eur. J. Org. Chem. 2015, 6801-6805. Abstract>
176) S. Nakanowatari, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Functionalizations with Allenes: Versatile Allenylations and Allylations" Chem. Eur. J. 2015, 21, 16246-16251. Abstract>
175) J. Li, L. Ackermann, "C-H activation: Following directions" Nat. Chem. 2015, 7, 686-687. Abstract>
174) J. Li, L. Ackermann, "Carboxylate-Assisted Ruthenium(II)-Catalyzed C-H Activations of Monodentate Amides with Conjugated Alkenes" Org. Chem. Front. 2015, 2, 1035-1039. Abstract>
173) S. Musa, A. Ghosh, L. Vaccaro, L. Ackermann, D. Gelman, "Efficient E-Selective Transfer Semihydrogenation of Alkynes by Means of Ligand-Metal Cooperating" Adv. Synth. Catal. 2015, 357, 2351-2357. Abstract>
172) J. Hubrich, T. Himmler, L. Rodefeld, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Arylation of Azoarenes by Carboxylate Assistance" ACS Catal. 2015, 5, 4089-4093. Abstract>
171) J. Li, L. Ackermann, "Cobalt(III)-Catalyzed Aryl and Alkenyl C-H Aminocarbonylation with Isocyanates and Acyl Azides" Angew. Chem. Int. Ed. 2015, 54, 8551-8554. Abstract>
170) Y. Zhu, M. Bauer, L. Ackermann, "Late-Stage Peptide Diversification by Bioorthogonal Catalytic C-H Arylation at 23 C in H2O" Chem. Eur. J. 2015, 21, 9980-9983. Abstract>
169) L. Wang, K. Rauch, A. V. Lygin, S. I. Kozhushkov, L. Ackermann, "Ruthenium-Catalyzed Direct Oxidative Alkenylation of Arenes by Twofold C-H Bond Functionalization in Water: Synthesis of Ethyl (E)-3-(2-Acetamido-4-methylphenyl)acrylate" Org. Synth. 2015, 92, 131-147. Abstract>
168) K. Graczyk, T. Haven, L. Ackermann, "Iron-Catalyzed C(sp2)-H and C(sp3)-H Methylations of Amides and Anilides" Chem. Eur. J. 2015, 21, 8812-8815. Abstract>
167) M. Moselage, N. Sauermann, J. Koeller, W. Liu, D. Gelman, L. Ackermann, "Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage" Synlett 2015, 1596-1600. Abstract>
166) W. Ma, L. Ackermann, "Cobalt(II)-Catalyzed Oxidative C-H Alkenylations: Regio- and Site-Selective Access to Isoindolin-1-one" ACS Catal. 2015, 5, 2822-2825. Abstract>
165) M. Moselage, N. Sauermann, S. C. Richter, L. Ackermann, "C-H Alkenylations with Alkenyl Acetates, Phosphates, Carbonates and Carbamates by Versatile Cobalt Catalysis at 23 C" Angew. Chem. Int. Ed. 2015, 54, 6352-6355. Abstract> (Selected as hot paper)
164) S. Warratz,' C. Kornhaa ,' A. Cajaraville, B. Niep tter, D. Stalke, L. Ackermann "Ruthenium(II)-Catalyzed C-H Activation/Alkyne Annulation with O2 as the Sole Oxidant by Weak-Coordination" Angew. Chem. Int. Ed. 2015, 54, 5513-5517. 'Both authors contributed equally. Abstract>(Selected as hot paper)
163) J. Li, L. Ackermann, "Cobalt-Catalyzed C-H Arylations with Weakly-Coordinating Amides and Tetrazoles: Expedient Route to Angiotensin-II-Receptor Blockers" Chem. Eur. J. 2015, 21, 5718-5722. Abstract>
162) C. Tirler, L. Ackermann, "Ruthenium(II)-Catalyzed Cross-Dehydrogenative C-H Alkenylations by Triazole Assistance" Tetrahedron (Symposia in print) 2015, 4543-4551. Abstract>
161) W. Liu, D. Zell, M. John, L. Ackermann, "Manganese-Catalyzed Synthesis of cis-β-Amino Acid Esters through Organometallic C-H Activation of Ketimines" Angew. Chem. Int. Ed. 2015, 54, 4092-4096. Abstract>
160) L. Ackermann, "Robust Ruthenium(II)-Catalyzed C-H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers" Org. Process Res. Dev. 2015, 18, 260-269. Abstract>
159) J. Li, L. Ackermann, "Cobalt-Catalyzed C-H Cyanation of Arenes and Heteroarenes" Angew. Chem. Int. Ed. 2015, 54, 3635-3638. Abstract> (Selected as hot paper)
158) J. Hubrich, T. Himmler, L. Rodefeld, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Arylation of Anilides with Boronic Acids, Borinic Acids and Potassium Trifluoroborates" Adv. Synth. Catal. 2015, 357, 474-480. Abstract>
157) K. Raghuvanshi, K. Rauch, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Acyloxylation of Phenols with Removable Auxiliary" Chem. Eur. J. 2015, 21, 1790-1794. Abstract>
156) F. Yang, L. Ackermann, "Dehydrative C-H/N-OH Functionalizations in H2O by Ruthenium(II)-Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight" J. Org. Chem. 2014, 79, 12070-12082. Abstract>
155) W. Ma, R. Mei, G. Tenti, L. Ackermann, "Ruthenium(II)-Catalyzed Oxidative C-H Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides" Chem. Eur. J. 2014, 20, 15248-15251. Abstract>
154) F. Yang, K. Rauch, K. Kettelhoit, L. Ackermann, "Aldehyde-Assisted Ruthenium(II)-Catalyzed C-H Oxygenations" Angew. Chem. Int. Ed. 2014, 53, 11285-11288. Abstract> (Selected as hot paper)
153) Y. Zhu, M. Bauer, J. Ploog, L. Ackermann, "Late-Stage Diversification of Peptides by Metal-free C-H Arylation" Chem. Eur. J. 2014, 20, 13099-13102. Abstract>
152) S. De Sarkar, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Activation with Isocyanates: Versatile Route to Phthalimides" Chem. Eur. J. 2014, 20, 13932-13936. Abstract>
151) L. Ackermann, "Cobalt-Catalyzed C-H Arylations, Benzylations and Alkylations with Organic Electrophiles and Beyond" J. Org. Chem. 2014, 79, 8948-8954. Abstract>
150) H. H. Al Mamari, E. Diers, L. Ackermann, "Triazole-Assisted Ruthenium-Catalyzed C-H Arylation of Aromatic Amides" Chem. Eur. J. 2014, 20, 9739-9743. Abstract>
149) S. De Sarkar, W. Liu, S. I. Kozhushkov, L. Ackermann, "Weakly Coordinating Directing Groups for Ruthenium(II)-Catalyzed C-H Activation" Adv. Synth. Catal. 2014, 356, 1461-1479. Abstract>
148) W. Ma, L. Ackermann, "Silver-Mediated Alkyne Annulations by C-H/P-H Functionalizations: Step-Economical Access to Benzophospholes" Synthesis 2014, 2297-2304. Abstract>
147) S. Nakanowatari, L. Ackermann, "Ruthenium(II)-Catalyzed Synthesis of Isochromenes by C-H Activation with Weakly-Coordinating Aliphatic Hydroxyl Groups" Chem. Eur. J. 2014, 20, 5409-5413. Abstract>
146) M. Schinkel, L. Wang, K. Bielefeld, L. Ackermann, "Ruthenium(II)-Catalyzed C(sp3)-H α-Alkylation of Pyrrolidines" Org. Lett. 2014, 16, 1876-1879. Abstract>
145) Q. Gu, H. H. Al Mamari, K. Graczyk, E. Diers, L. Ackermann, "Iron-Catalyzed C(sp2)-H and C(sp3)-H Arylation by Triazole Assistance" Angew. Chem. Int. Ed. 2014, 53, 3868-3871. Abstract> (highlighted in Synfacts 2014, 735)
144) C. Kornhaa , C. Kuper, L. Ackermann, "Ferrocenylalkynes for Ruthenium-Catalyzed Isohypsic C-H/N-O Bond Functionalizations" Adv. Synth. Catal. 2014, 356, 1619-1624. Abstract>
143) J. Li, M. John, L. Ackermann, "Amidines for Versatile Ruthenium(II)-Catalyzed Oxidative C-H Activations with Internal Alkynes and Acrylates" Chem. Eur. J. 2014, 20, 5403-5408. Abstract>
142) W. Liu, L. Ackermann, "Versatile Ruthenium(II)-Catalyzed C-H Cyanations of Benzamides" Chem. Commun. 2014, 50, 1878-1881. Abstract>
141) W. Song, S. Lackner, L. Ackermann, "Nickel-Catalyzed C-H Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes" Angew. Chem. Int. Ed. 2014, 53, 2477-2480. Abstract> (Selected as hot paper)
140) A. Masarwa, D. Didier, T. Zabrodski, M. Schinkel, L. Ackermann, I. Marek, "Merging allylic carbon-hydrogen and selective carbon-carbon bond activation" Nature 2014, 505, 199-203. Abstract>
139) K. C. Mondal, P. P. Samuel, Y. Li, H. W. Roesky, S. Roy, L. Ackermann, N. S. Sidhu, G. M. Sheldrick, E. Carl, S. Demeshko, S. De, P. Parameswaran, L. Ungur, L. F. Chibotaru, D. M. Andrada, "A Catalyst with Two-Coordinate Nickel: Theoretical and Catalytic Studies" Eur. J. Inorg. Chem. 2014, 818-823. Abstract>
138) L. Ackermann, "Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C-H/Het-H Bond Functionalizations" Acc. Chem. Res. 2014, 47, 281-295. Abstract>
137) L. Wang, L. Ackermann, "Ruthenium-Catalyzed ortho-C-H Halogenations of Benzamides" Chem. Commun. 2014, 50, 1083-1085. Abstract>
136) V. S. Thirunavukkarasu, S. I. Kozhushkov, L. Ackermann, "C-H Nitrogenation and Oxygenation by Ruthenium Catalysis" Chem. Commun. 2014, 50, 29-39. Abstract>
135) J. Li, L. Ackermann, "Ruthenium-Catalyzed Oxidative Alkyne Annulation by C-H Activation on Ketimines" Tetrahedron 2014, 70, 3342-3348. Abstract>
134) S. Musa, O. A. Filippov, N. V. Belkova, E. S. Shubina, G. A. Silantyev, L. Ackermann, D. Gelman, "Ligand-Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation" Chem. Eur. J. 2013, 19, 16906-16909. Abstract>
133) S. Musa, L. Ackermann, D. Gelman, "Dehydrogenative Cross-Coupling of Primary and Secondary Alcohols" Adv. Synth. Catal. 2013, 355, 3077-3080. Abstract>
132) W. Ma, L. Ackermann, "Ruthenium(II)-Catalyzed C-H Alkenylations of Phenols with Removable Directing Groups" Chem. Eur. J. 2013, 19, 13925-13928. Abstract>
131) M. Schinkel, J. Wallbaum, S. I. Kozhushkov, I. Marek, L. Ackermann, "Carboxylate-Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes" Org. Lett. 2013, 15, 4482-4484. Abstract>
130) B. Punji, W. Song, G. A. Shevchenko, L. Ackermann, "Cobalt-Catalyzed C-H Bond Functionalizations with Aryl and Alkyl Chlorides" Chem. Eur. J. 2013, 19, 10605-10610. Abstract> (highlighted in ChemistryViews)
129) W. Liu, L. Ackermann, "Ortho- and Para-Selective Ruthenium-Catalyzed C(sp2)-H Oxygenations of Phenol Derivatives" Org. Lett. 2013, 15, 3484-3486. Abstract>
128) W. Song, L. Ackermann, "Nickel-Catalyzed Alkyne Annulation by Anilines: Versatile Indole Synthesis by C-H/N-H Functionalization" Chem. Commun. 2013, 49, 6638-6640. Abstract>
127) V. S. Thirunavukkarasu, K. Raghuvanshi, L. Ackermann, "Expedient C-H Amidations of Heteroaryl Arenes Catalyzed by Versatile Ruthenium(II) Catalysts" Org. Lett. 2013, 15, 3286-3289. Abstract>
126) W. Song, S. I. Kozhushkov, L. Ackermann, "Site-Selective Catalytic C(sp2)-H Bond Azidations" Angew. Chem. Int. Ed. 2013, 52, 6576-6578. Abstract>
125) N. Y. P. Kumar, R. Jeyachandran, L. Ackermann, "C(sp3)-H Bond Arylations Catalyzed by Well-Defined [Ru(O2CMes)2(p-cymene)]" J. Org. Chem. 2013, 78, 4145-4152. Abstract>
124) N. Hofmann, L. Ackermann, "meta-Selective C-H Bond Alkylation with Secondary Alkyl Halides" J. Am. Chem. Soc. 2013, 135, 5877-5884. Abstract>
123) M. Schinkel, I. Marek, L. Ackermann, "Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes through C-H Cleavage" Angew. Chem. Int. Ed. 2013, 52, 3977-3980. Abstract>
122) F. Yang, L. Ackermann, "Ruthenium-Catalyzed C-H Oxygenation on Aryl Weinreb Amides" Org. Lett. 2013, 15, 718-720. Abstract>
121) E. Diers, N. Y. P. Kumar, T. Mejuch, I. Marek, L. Ackermann, "Carboxylate-assisted ruthenium(II)-catalyzed C-H arylations of 5-aryl tetrazoles: Step-economical access to Valsartan" Tetrahedron 2013, 69, 4445-4453. Abstract>
120) L. Wang, L. Ackermann, "Versatile Pyrrole Synthesis through Ruthenium(II)-Catalyzed Alkene C-H Bond Functionalization on Enamines" Org. Lett. 2013, 15, 176-179. Abstract>
119) S. I. Kozhushkov, L. Ackermann, "Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C-H bond functionalization" Chem. Sci. 2013, 4, 886-896. Abstract>
118) S. I. Kozhushkov, H. K. Potukuchi, L. Ackermann, "Direct C-H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles" Catal. Sci. Technol. 2013, 3, 562-571. Abstract>
117) M. Deponti, S. I. Kozhushkov, D. S. Yufit, L. Ackermann, "Ruthenium-catalyzed C-H/O-H and C-H/N-H bond functionalizations: Oxidative annulations of cyclopropyl-substituted alkynes" Org. Biomol. Chem. 2013, 11, 142-148. Abstract>
116) W. Ma, K. Graczyk, L. Ackermann, "Ruthenium-Catalyzed Alkyne Annulations with Substituted 1H-Pyrazoles by C-H/N-H Bond Functionalizations" Org. Lett. 2012, 14, 6318-6321. Abstract>
115) V. S. Thirunavukkarasu, L. Ackermann, "Ruthenium-Catalyzed C-H Bond Oxygenations with Weakly-Coordinating Ketones" Org. Lett. 2012, 14, 6206-6209. Abstract>
114) J. Li, C. Kornhaa , L. Ackermann, "Ruthenium-catalyzed oxidative C-H alkenylation of aryl carbamates" Chem. Commun. 2012, 48, 11343-11345. Abstract>
113) C. Kornhaa , J. Li, L. Ackermann, "Cationic Ruthenium Catalysts for Alkyne Annulations with Oximes by C-H/N-O Functionalizations" J. Org. Chem. 2012, 77, 9190-9198. Abstract>
112) R. Jeyachandran, H. K. Potukuchi, L. Ackermann, "Copper-Catalyzed CuAAC/Intramolecular C-H Arylation Sequence: Synthesis of Annulated 1,2,3-Triazoles" Beilstein J. Org. Chem. 2012, 8, 1771-1777. Abstract>
111) V. S. Thirunavukkarasu, J. Hubrich, L. Ackermann, "Ruthenium-Catalyzed Oxidative C(sp2)-H Bond Hydroxylation: Site-Selective C-O Bond Formation on Benzamides" Org. Lett. 2012, 14, 4210-4213. Abstract>
110) L. Ackermann, S. I. Kozhushkov, D. S. Yufit, "Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes through C-H Bond Cleavages: Scope and Mechanism" Chem. Eur. J. 2012, 18, 12068-12077. Abstract>
109) K. Graczyk, W. Ma, L. Ackermann, "Oxidative Alkenylation of Aromatic Esters by Ruthenium-Catalyzed Twofold C-H Bond Cleavages" Org. Lett. 2012, 14, 4110-4113. Abstract> (highlighted in Synfacts 2012 1222)
108) W. Song, L. Ackermann, "Cobalt-Catalyzed Direct Arylation and Benzylation by C-H/C-O Cleavage with Sulfamates, Carbamates, and Phosphates" Angew. Chem. Int. Ed. 2012, 51, 8251-8254. Abstract>
107) V. S. Thirunavukkarasu, M. Donati, L. Ackermann, "Hydroxyl-Directed Ruthenium-Catalyzed C-H Bond Functionalization: Versatile Access to Fluorescent Pyrans" Org. Lett. 2012, 14, 3416-3419. Abstract> (highlighted in Synfacts 2012 1015)
106) L. Ackermann, V. P. Mehta, "Palladium-Catalyzed Mono-α-Arylation of Acetone with Aryl Imidazolylsulfonates" Chem. Eur. J. 2012, 18, 10230-10233. Abstract>
105) L. Ackermann, J. Pospech, H. K. Potukuchi, "Well-Defined Ruthenium(II) Carboxylate as Catalyst for Direct C-H/C-O Bond Arylations with Phenols in Water" Org. Lett. 2012, 14, 2146-2149. Abstract>
104) L. Ackermann, C. Kornhaa , Y. Zhu, "Palladium-Catalyzed Direct C-H Bond Alkynylations of Heteroarenes Using gem-Dichloroalkenes" Org. Lett. 2012, 14, 1824-1826. Abstract>
103) L. Ackermann, E. Diers, A. Manvar, "Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles" Org. Lett. 2012, 14, 1154-1157. Abstract> (Featured on Synform 06/12)
102) L. Ackermann, A. R. Kapdi, H. K. Potukuchi, S. I. Kozhushkov "Syntheses via C-H Bond Functionalizations", in Handbook of Green Chemistry (Volume-Eds.: C.-J. Li), Wiley-VCH, 2012, Weinheim, 259-305.
101) L. Ackermann, J. Pospech, K. Graczyk, K. Rauch, "Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C-H/O-H Bond Cleavages" Org. Lett. 2012, 14, 930-933. Abstract>
100) L. Ackermann, A. V. Lygin, "Cationic Ruthenium(II) Catalysts for Oxidative C-H/N-H Bond Functionalizations of Anilines with Removable Directing Group: Synthesis of Indoles in Water" Org. Lett. 2012, 14, 764-767. Abstract>
99) L. Ackermann, L. Wang, R. Wolfram, A. V. Lygin, "Ruthenium-Catalyzed Oxidative C-H Alkenylations of Anilides and Benzamides in Water" Org. Lett. 2012, 14, 728-731. Abstract>
98) L. Ackermann, L. Wang, A. V. Lygin, "Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles" Chem. Sci. 2012, 3, 177-180. Abstract> (highlighted by the Royal Society of Chemistry)
97) L. Ackermann, S. Fenner, "Ruthenium-Catalyzed C-H/N-O Bond Functionalization: Green Isoquinolone Syntheses in Water" Org. Lett. 2011, 13, 6548-6551. Abstract>
96) L. Ackermann, B. Punji, W. Song, "User-Friendly [(diglyme)NiBr2]-Catalyzed Direct Alkylations of Heteroarenes with Unactivated Alkyl Halides through C-H Bond Cleavages" Adv. Synth. Catal. 2011, 353, 3325-3329. Abstract>
95) L. Ackermann, J. Pospech, "Ruthenium-Catalyzed Oxidative C-H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones" Org. Lett. 2011, 13, 4153-4155. Abstract> (highlighted in Synfacts 2011, 1167)
94) L. Ackermann, A. V. Lygin, N. Hofmann, "Ruthenium-Catalyzed Oxidative Annulation via C-H/N-H Bond Cleavages" Angew. Chem. 2011, 123, 6503-6506; Angew. Chem. Int. Ed. 2011, 50, 6379-6382. Abstract> (selected as hot paper)
93) L. Ackermann, A. V. Lygin, "Ruthenium-Catalyzed Direct C-H Bond Arylations of Heteroarenes" Org. Lett. 2011, 13, 3332-3335. Abstract>
92) L. Ackermann, A. V. Lygin, N. Hofmann, "Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C-H/N-H Bond Functionalizations" Org. Lett. 2011, 13, 3278-3281. Abstract> (highlighted in Synfacts 2011, 837)
91) L. Ackermann, S. Barf er, C. Kornhaa , A. R. Kapdi, "C-H Bond Arylations and Benzylations on Oxazol(in)es with a Palladium Catalyst of a Secondary Phosphine Oxide" Org. Lett. 2011, 13, 3082-3085. Abstract>
90) L. Ackermann, S. I. Kozhushkov, D. S. Yufit, I. Marek, "Efficient Bronsted Acid Catalyzed Hydrations and Hydroaminations of (Dicyclopropylmethylene)cyclopropane" Synlett 2011, 1515-1518. Abstract>
89) L. Ackermann, M. Dell'Acqua, S. Fenner, R. Vicente, R. Sandmann, "Metal-Free Direct Arylations of Indoles and Pyrroles with Diaryliodonium Salts" Org. Lett. 2011, 13, 2358-2360. Abstract>
88) L. Ackermann, "Transition-Metal-Catalyzed Carboxylation of C-H Bonds" Angew. Chem. 2011, 123, 3926-3928; Angew. Chem. Int. Ed. 2011, 50, 3842-3844. Abstract>
87) L. Ackermann, N. Hofmann, R. Vicente, "Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines" Org. Lett. 2011, 13, 1875-1877. Abstract>
86) L. Ackermann, "Carboxylate-Assisted Transition Metal-Catalyzed C-H Bond Functionalizations: Mechanism and Scope" Chem. Rev. 2011, 111, 1315-1345. Abstract>
85) L. Ackermann, R. Sandmann, W. Song, "Palladium- and Nickel-Catalyzed Aminations of Aryl Imidazolylsulfonates and Sulfamates" Org. Lett. 2011, 13, 1784-1786. Abstract>
84) L. Ackermann, A. R. Kapdi, S. Fenner, C. Kornhaa , C. Schulzke, "Well-Defined Air-Stable Palladium HASPO-Complexes for Efficient Kumada-Corriu Cross-Couplings of (Hetero)Aryl or Alkenyl Tosylates" Chem. Eur. J. 2011, 17, 2965-2971. Abstract>
83) L. Ackermann, H. K. Potukuchi, "1,3-Bis-(2,6-diisopropylphenyl)-[1,3,2]diazaphospholidine 2-oxide" e-EROS 2011, DOI: 10.1002/047084289X.rn01344. Abstract>
82) L. Ackermann, W. Song, R. Sandmann, "Nickel-Catalyzed, Base-Mediated Amination/Hydroamination Reaction Sequence for a Modular Synthesis of Indoles" J. Organomet. Chem. 2011, 696, 195-201. Abstract>
81) L. Ackermann, S. Fenner, "Direct Arylations of Electron-Deficient (Hetero)Arenes with Aryl or Alkenyl Tosylates and Mesylates" Chem. Commun. 2011, 47, 430-432. Abstract>
80) A. Wolpers, L. Ackermann, P. Vana, "H-Phosphonic Acid Derivatives as Catalysts for Reversible Chain Transfer Catalyzed Polymerization (RTCP) at Ambient and High Pressure" Macromol. Chem. and Phys. 2011, 212, 259-265. Abstract>
79) L. Ackermann, "Air-Stable Bifunctional HASPO Preligands for Metal-Catalyzed Cross-Couplings and Direct C-H Bond Arylations" Isr. J. Chem. 2010, 50, 652-663. Abstract>
78) L. Ackermann, R. Vicente, H. K. Potukuchi, V. Pirovano, "Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts" Org. Lett. 2010, 12, 5032-5035. Abstract>
77) L. Ackermann, H. K. Potukuchi, "Regioselective syntheses of fully-substituted 1,2,3-triazoles: the CuAAC/C-H bond functionalization nexus", Org. Biomol. Chem. 2010, 8, 4503-4513. Abstract>
76) L. Ackermann, "Metal-catalyzed direct alkylations of (hetero)arenes via C-H bond cleavages with unactivated alkyl halides", Chem. Commun. 2010, 46, 4866-4877. Abstract>
75) L. Ackermann, R. Vicente, "Ruthenium-Catalyzed Direct Arylations through C-H Bond Cleavages" Top. Curr. Chem. 2010, 292, 211-229. Abstract>
74) L. Ackermann, A. R. Kapdi, C. Schulzke, "Air-Stable Secondary Phosphine Oxide or Chloride (Pre)Ligands for Cross-Couplings of Unactivated Alkyl Chlorides" Org. Lett. 2010, 12, 2298-2301. Abstract>
73) L. Ackermann, P. Nov k, R. Vicente, V. Pirovano, H. K. Potukuchi, "Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations" Synthesis 2010, 2245-2253. Abstract>
72) L. Ackermann, R. Jeyachandran, H. K. Potukuchi, P. Nov k, L. B ttner, "Palladium-Catalyzed Dehydrogenative Direct Arylations of 1,2,3-Triazoles" Org. Lett. 2010, 12, 2056-2059. Abstract>
71) L. Ackermann, "Transition Metal-Catalyzed Direct Arylations via C-H Bond Cleavages" Pure Appl. Chem. 2010, 82, 1403-1413. Abstract>
70) L. Ackermann, H. K. Potukuchi, A. R. Kapdi, C. Schulzke, "Kumada-Corriu Cross-Couplings with 2-Pyridyl Grignard Reagents" Chem. Eur. J. 2010, 16, 3300-3303. Abstract>
69) L. Ackermann, H. K. Potukuchi, A. Althammer, R. Born, P. Mayer, "Tetra-ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki-Miyaura Couplings with a Diaminochlorophosphine Ligand" Org. Lett. 2010, 12, 1004-1007. Abstract>
68) L. Ackermann, S. Barf er, J. Pospech, "Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C-H Bond Cleavages with Sulfamates or Phosphates as Electrophiles" Org. Lett. 2010, 12, 724-726. Abstract> (highlighted in Synfacts 2010, 694)
67) L. Ackermann, C. Wechsler, A. R. Kapdi, A. Althammer, "Air-Stable Diaminophosphine Sulfides as Preligands for Nickel-Catalyzed Cross-Couplings of Unactivated Fluoro(hetero)arenes" Synlett 2010, 294-298. Abstract>
66) L. Ackermann, R. Vicente, A. Kapdi, "Transition-Metal-Catalyzed Direct Arylations of (Hetero)Arenes via C-H Bond Cleavage" Angew. Chem. 2009, 121, 9976-10011; Angew. Chem. Int. Ed. 2009, 48, 9792-9826. Abstract>
65) L. Ackermann, P. Nov k, "Regioselective Ruthenium-Catalyzed Direct Benzylations of Arenes through C-H Bond Cleavages" Org. Lett. 2009, 11, 4966-4969. Abstract>
64) L. Ackermann, R. Vicente, "Catalytic Direct Arylations in Polyethylene Glycol (PEG): Recyclable Palladium(0) Catalyst for C-H Bond Cleavages in the Presence of Air" Org. Lett. 2009, 11, 4922-4925. Abstract> (highlighted in Synfacts 2010, 362; highlighted in Organic Chemistry Portal)
63) L. Ackermann, R. Vicente, N. Hofmann, "Air-Stable Secondary Phosphine Oxide as Preligand for Palladium-Catalyzed Intramolecular α-Arylations with Chloroarenes" Org. Lett. 2009, 11, 4274-4276. Abstract> highlighted in Organic Chemistry Portal)
62) L. Ackermann, H. K. Potukuchi, "Palladium-Catalyzed Cross-Coupling Reactions of 2-Pyridylborates with Air-Stable HASPO Preligands" Synlett 2009, 2852-2856. Abstract>
61) L. Ackermann, P. Nov k, R. Vicente, N. Hofmann, "Ruthenium-Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through C-H Bond Cleavage" Angew. Chem. 2009, 121, 6161-6164; Angew. Chem. Int. Ed. 2009, 48, 6045-6048. Abstract> (Selected as hot paper)
60) L. Ackermann, A. Althammer, Peter Mayer, "Palladium-Catalyzed Direct Arylation-Based Domino Synthesis of Annulated N-Heterocycles Using Alkenyl or (Hetero)Aryl 1,2-Dihalides" Synthesis 2009, 3493-3503. Abstract> highlighted in Organic Chemistry Portal)
59) L. Ackermann, R. Sandmann, M. Schinkel, M. V. Kondrashov, "Palladium-Catalyzed Sequential Indole Synthesis Using Sterically Hindered Amines" Tetrahderon (Symposia in print) 2009, 65, 8930-8939. Abstract>
58) L. Ackermann, S. Barf er, H. K. Potukuchi, "Copper-Catalyzed N-Arylation/Hydroamin(d)ation Domino Synthesis of Indoles and its Application to the Preparation of a Chek1/KDR Kinase Inhibitor Pharmacophore" Adv. Synth. Catal. 2009, 351, 1064-1072. Abstract> (highlighted in Synfacts 2009, 836)
57) L. Ackermann, S. Barf er, H. K. Potukuchi, "Copper-Catalyzed N-Arylation/Hydroamin(d)ation Domino Synthesis of Indoles and its Application to the Preparation of a Chek1/KDR Kinase Inhibitor Pharmacophore" Adv. Synth. Catal. 2009, 351, 1064-1072. Abstract>
56) L. Ackermann, R. Sandmann, L. T. Kaspar, "Two Titanium-Catalyzed Reaction Sequences for Syntheses of Pyrroles from (E/Z)-Chloroenynes or α-Haloalkynols" Org. Lett. 2009, 11, 2031-2034. Abstract> (highlighted in Synfacts 2009, 718)
55) L. Ackermann, R. Sandmann, M. V. Kondrashov, "Thieme chemistry journal awardees - where are they now? Palladium-Catalyzed N-Arylation/Hydroamination Sequence for the Synthesis of Indoles with Sterically Demanding N-Substiuents" Synlett 2009, 1219-1222. Abstract>
54) L. Ackermann, R. Born, R. Vicente, "Ruthenium-Catalyzed Direct Arylations of N-Aryl 1,2,3-Triazoles with Aryl Chlorides as Electrophiles" ChemSusChem 2009, 546-549. Abstract>
53) L. Ackermann, A. Althammer, S. Fenner, "Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates" Angew. Chem. 2009, 121, 207-210; Angew. Chem. Int. Ed. 2009, 48, 201-204. Abstract> (Selected as hot paper) (Highlighted in Synfacts 2009, 260)
52) L. Ackermann, A. Althammer, "Moderne Magnesiumorganische Chemie. Neues von der Grignard-Reaktion", Chem. Unserer Zeit 2009, 43, 74-83. Abstract>
51) L. Ackermann, S. Barf er, "Palladium-Catalyzed Direct C-3 Arylations of Indoles with an Air-Stable HASPO" Synlett 2009, 808-812. Abstract>
50) L. Ackermann, R. Vicente, "Sustainable Ruthenium-Catalyzed Direct Arylations through C-H Bond Functionalizations", in Experiments in Green and Sustainable Chemistry (Eds.: H. W. Roesky, D. Kennepohl), Wiley-VCH, Weinheim, 2009, 64-69.
49) L. Ackermann, R. Born, "Mizoroki-Heck Reactions with Metals other than Palladium", in The Mizoroki-Heck Reaction (Ed.: M. Oestreich), Wiley, Chichester, 2009, 383-403.
48) L. Ackermann, R. Vicente, "Metal-Catalyzed Direct Arylations", in Modern Arylation Methods (Ed.: L. Ackermann), Wiley-VCH, Weinheim, 2009, 311-333.
47) L. Ackermann, "Arylation Reactions: A Historical Perspective", in Modern Arylation Methods (Ed.: L. Ackermann), Wiley-VCH, Weinheim, 2009, 1-24.
46) L. Ackermann (Ed.), "Modern Arylation Methods", Wiley-VCH, Weinheim, January 2009, 543 pages. ISBN: 978-3-527-31937-4.
45) L. Ackermann, M. Mulzer, "Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C-H and C-OH Bond Functionalizations" Org. Lett. 2008, 10, 5043-5045.Abstract>
44) S. I. Kozhushkov, D. S. Yufit, L. Ackermann, "Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes: Mild C-H Bond Functionalizations with Conservation of Cyclopropane Rings" Org. Lett. 2008, 10, 3409-3412. Abstract>
43) L. Ackermann, H. K. Potukuchi, D. Landsberg, R. Vicente, "Copper-Catalyzed "Click" Reaction/Direct Arylation Sequence: Modular Syntheses of 1,2,3-Triazoles" Org. Lett. 2008, 10, 3081-3084. Abstract> highlighted in Organic Chemistry Portal) (among the most cited publications in 2008-2010)
42) L. Ackermann, R. Vicente, A. Althammer, "Assisted Ruthenium-Catalyzed C-H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents" Org. Lett. 2008, 10, 2299-2302. Abstract> (the most cited publication in 2008-2010)
41) L. Ackermann, A. Althammer, R. Born, "[RuCl3(H2O)n]-catalyzed direct arylations" Tetrahedron (Symposia in print) 2008, 64, 6115-6124. Abstract>
40) L. Ackermann, "Chiral Secondary Phosphine Oxides as Preligands", in Trivalent Phosphorus Compounds in Asymmetric Catalysis, Synthesis and Applications Ed.: A. B rner), Wiley-VCH, Weinheim, 2008, 831-847.
39) L. Ackermann, A. Althammer "Phosphoric Acid Diesters as Efficient Catalysts for Hydroaminations of Nonactivated Alkenes and an Application to Asymmetric Hydroaminations", Synlett 2008, 995-998. Abstract> (highlighted in Synfacts 2008, 639)
38) L. Ackermann, R. Vicente, R. Born, "Palladium-Catalyzed Direct Arylations of 1,2,3-Triazoles with Aryl Chlorides Using Conventional Heating" Adv. Synth. Catal. 2008, 350, 741-748. Abstract> (the most cited publication in 2007-2008)
37) L. Ackermann, R. Sandmann, A. Villar, L. T. Kaspar, "Annulation of internal alkynes through a hydroamination/aza-Heck reaction sequence for the regioselective synthesis of indoles" Tetrahedron (Symposia in print) 2008, 64, 769-777. Abstract> (Highlighted in Synfacts 2008, 355)
36) L. Ackermann, "Chelation-Assisted Arylation via C-H Bond Cleavage", in Top. Organomet. Chem. 2007, 24, 35-60. Abstract>
35) L. Ackermann, A. Althammer, R. Born, "[RuCl3(H2O)n]-Catalyzed Direct Arylations with Bromides as Electrophiles" Synlett 2007, 2833-2836. Abstract>
34) L. Ackermann, R. Born, P. lvarez-Bercedo, "Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis" Angew. Chem. 2007, 119, 6482-6485; Angew. Chem. Int. Ed. 2007, 46, 6364-6367. Abstract> (Selected as hot paper)
33) L. Ackermann, L. T. Kaspar, "TiCl4-Catalyzed Indirect Anti-Markovnikov Hydration of Alkynes: Application to the Synthesis of Benzo[b]furans" J. Org. Chem. 2007, 72, 6149-6153. Abstract> highlighted in Organic Chemistry Portal)
32) L. Ackermann, L. T. Kaspar, A. Althammer, "Hydroaminations of Unactivated Alkenes with Basic Alkylamines: Group 4 Metal Halide Catalysts and Bronsted-Acid Organocatalysts" Org. Biomol. Chem. 2007, 5, 1975-1978. Abstract>
31) L. Ackermann, A. Althammer "Domino NH/CH Bond Activation: Palladium-Catalyzed Synthesis of Annulated Heterocycles Using Dichloro(hetero)arenes" Angew. Chem. 2007, 119, 1652-1654; Angew. Chem. Int. Ed. 2007, 46, 1627-1629. Abstract> (Selected as hot paper)
30) L. Ackermann, "Catalytic Arylations with Challenging Substrates: From Air-Stable HASPO Preligands to Indole Syntheses and C-H-Bond Functionalizations" Synlett 2007, 507-526. Abstract>
29) L. Ackermann, J. H. Spatz, C. J. Gschrei, R. Born, A. Althammer, "A Diaminochlorophosphine for Palladium-Catalyzed Arylations of Amines and Ketones" Angew. Chem. 2006, 118, 7789-7792; Angew. Chem. Int. Ed. 2006, 45, 7627-7630. Abstract>
28) L. Ackermann, A. Althammer, "Air-Stable PinP(O)H as Preligand for Palladium-Catalyzed Kumada Couplings of Unactivated Tosylates" Org. Lett. 2006, 8, 3457-3460. Abstract> highlighted in Organic Chemistry Portal)
27) L. Ackermann, A. Althammer, "One-Pot 2-Aryl/Vinylindole Synthesis Consisting of a Ruthenium-Catalyzed Hydroamination and a Palladium-Catalyzed Heck Reaction Using 2-Chloroaniline" Synlett 2006, 3125-3129. Abstract>
26) L. Ackermann, C. J. Gschrei, A. Althammer, M. Riederer, "Cross-coupling reactions of aryl and vinyl chlorides catalyzed by a palladium complex derived from an air-stable H-phosphonate" Chem. Commun. 2006, 1419-1421. Abstract>
25) L. Ackermann, "Air- and Moisture-Stable Secondary Phosphine Oxides as Preligands in Catalysis" Synthesis 2006, 1557-1571. Abstract>
24) L. Ackermann, A. Althammer, R. Born, "Catalytic Arylation Reactions by C-H Bond Activation with Aryl Tosylates" Angew. Chem. 2006, 118, 2681-2685; Angew. Chem. Int. Ed. 2006, 45, 2619-2622. Abstract>
23) L. Ackermann, R. Born, J. H. Spatz, A. Althammer, C. J. Gschrei "Air-Stable Phosphine Oxides as Preligands for Catalytic Activation Reactions of C-Cl-, C-F- and C-H-Bonds" Pure Appl. Chem. 2006, 78, 209-214. Abstract>
22) L. Ackermann, R. Born, J. H. Spatz, D. Meyer, "Efficient Aryl-(Hetero)Aryl Coupling via Activation of C-Cl and C-F Bonds Using Nickel Complexes of Air-Stable Phosphine Oxides" Angew. Chem. 2005, 117,7382-7386; Angew. Chem. Int. Ed. 2005, 44, 7216-7219.Abstract> (Selected as hot paper)
21) L. T. Kaspar, L. Ackermann, "Three-component indole synthesis using ortho-dihaloarenes" Tetrahedron (Symposia in print) 2005, 61, 11311-11316. Abstract> highlighted in Organic Chemistry Portal)
20) L. T. Kaspar, B. Fingerhut, L. Ackermann, "Titanium-Catalyzed Intermolecular Hydroamination of Vinylarenes" Angew. Chem. 2005, 117, 6126-6128; Angew. Chem. Int. Ed. 2005, 44, 5972-5974. Abstract>
19) L. Ackermann, "Phosphine Oxides as Preligands in Ruthenium-Catalyzed Arylations via C-H-Bond Functionalization Using Aryl Chlorides" Org. Lett. 2005, 7, 3123-3125. Abstract>
18) L. Ackermann, R. Born, "Modular Diamino and Dioxophosphine Oxides and Chlorides as Ligands for Transition-Metal-Catalyzed C-C and C-N Bond Formations Using Aryl Chlorides" Angew. Chem. 2005, 117, 2497-2500; Angew. Chem. Int. Ed. 2005, 44, 2444-2447. Abstract>
17) L. Ackermann, "General and Efficient Indole Syntheses Based on Catalytic Amination Reactions", Org. Lett. 2005, 7, 439-442. Abstract>
16) L. Ackermann, L. T. Kaspar, C. J. Gschrei, "Hydroamination/Heck reaction sequence for a highly regioselective one-pot synthesis of indoles using 2-chloroaniline", Chem. Commun. 2004, 2824-2825. Abstract>
15) L. Ackermann, R. Born, "TiCl4/t-BuNH2 as the sole catalyst for a hydro amination-based Fischer indole synthesis", Tetrahderon Lett. 2004, 45, 9541-9544. Abstract>
14) L. Ackermann, L. T. Kaspar, C. J. Gschrei "TiCl4-Catalyzed Intermolecular Hydroamination Reactions of Norbornene", Org. Lett. 2004, 6, 2515-2518. Abstract>
13) L. Ackermann, "TiCl4-catalyzed Intermolecular Hydroamination Reactions", Organometallics 2003, 22, 4367-4368. Abstract>
12) L. Ackermann, R. G. Bergman, R. N. Loy, "Use of Group 4 Bis(sulfonamido) Complexes in the Intramolecular Hydroamination of Alkynes and Allenes", J. Am. Chem. Soc. 2003, 125, 11956-11963. Abstract>
11) L. Ackermann, R. G. Bergman, "A Highly Reactive Titanium Precatalyst for Intramolecular Hydroamination Reactions", Org. Lett. 2002, 4, 1475-1478. Abstract>
10) A. F rstner, H. Krause, L. Ackermann, C. W. Lehmann, "N-Heterocyclic carbenes can coexist with alkenes and C-H acidic sites", Chem. Commun. 2001, 2240-2241. Abstract>
9) A. F rstner, L. Ackermann, B. Gabor, R. Goddard, C. W. Lehmann, R. Mynott, F. Stelzer, O. R. Thiel, "Comparative Investigation of Ruthenium-Based Metathesis Catalysts Bearing N-Heterocyclic Carbene (NHC) Ligands", Chem. Eur. J. 2001, 7, 3236-3253. Abstract>
8) A. F rstner, L. Ackermann, K. N. Beck, H. Hori, D. Koch, K. Langemann, M. Liebl, C. Six, W. Leitner, "Olefin Metathesis in Supercritical Carbon Dioxide", J. Am. Chem. Soc. 2001, 123, 9000-9006. Abstract>
7) L. Ackermann, C. Bruneau, P. H. Dixneuf, "Simple New Three-component Catalytic System for Enyne Metathesis ", Synlett 2001, 397-399. Abstract>
6) A. F rstner, O. R. Thiel, L. Ackermann, "Exploiting the Reversibility of Olefin Metathesis. Synthesis of Macrocyclic Trisubstituted Alkenes and (R,R)-(-)-Pyrenophorin", Org. Lett. 2001, 3, 449-451. Abstract>
5) L. Ackermann, D. El Tom, A. F rstner, "Ruthenium Carbene Complexes with Imidazol-2-ylidene Ligands: Syntheses of Conduritol Derivatives Reveals Superior RCM Activity", Tetrahderon 2000, 56, 2195-2202. Abstract>
4) A. F rstner, O. R. Thiel, L. Ackermann, H.-J. Schanz, S. P. Nolan, "Ruthenium Carbene Complexes with N,N'-Bis(mesityl)imidazol-2-ylidene Ligands: RCM Catalysts of Extended Scope", J. Org. Chem. 2000, 65, 2204-2207. Abstract>
3) L. Ackermann, A. F rstner, T. Weskamp, F. J. Kohl, W. A. Herrmann, "Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by ring-closing metathesis (RCM)", Tetrahedron Lett. 1999, 40, 4787-4790. Abstract>
2) A. F rstner, L. Ackermann, "A most user-friendly protocol for ring-closing metathesis reactions", Chem. Commun. 1999, 95-96. Abstract>
1) L. Ackermann, A. Heidbreder, F. Wurche, F.-G. Kl rner, J. Mattay, "Mechanistic Studies on PET-oxidative cyclization of unsaturated silyl enol ethers: dependence of the regioselectivity on alcohol addition and pressure effects", Perkin Trans. 2 1999, 863-869. Abstract>
L. Ackermann, CCS Chem. 2022, 4. (author profile) Abstract>
L. Ackermann, Angew. Chem. Int. Ed. 2010, 49, 3716. (author profile) Abstract>
A. Althammer, L. Ackermann, "Hochschule trifft Industrie" Nachr. Chem. 2008, 56, 71.
L. Ackermann, "The Claisen Rearrangement. Methods and Applications" Nachr. Chem. 2007, 55, 899.
L. Ackermann, "B rgenstock 2005" Nachr. Chem. 2005, 53, 817.
L. Ackermann, "Development of Air-Stable Heteroatom-Substituted Secondary Phosphine Oxides (HASPO) as Preligands for Catalytic Coupling Reactions" - Habilitation, M nchen 2007.
L. Ackermann, "Entwicklung und Anwendung neuartiger Pr katalysatoren f r die Olefinmetathese" - Dissertation, Der Andere Verlag 2001, ISBN: 3935316585.